triethyl(3-methylphenoxy)silane

Base Information

• Chemical Name: triethyl(3-methylphenoxy)silane
• CAS No.: 18406-01-4
• Molecular Formula: C₁₃H₂₂OSi
• Molecular Weight: 222.403
• Mol file: 18406-01-4.mol

Synonyms:triethyl(3-methylphenoxy)silane

Chemical Property of triethyl(3-methylphenoxy)silane

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of triethyl(3-methylphenoxy)silane

There total 3 articles about triethyl(3-methylphenoxy)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

triethylsilane (617-86-7) + 3-methyl-phenol (108-39-4) → triethyl(3-methylphenoxy)silane (18406-01-4)

Guidance literature:

With potassium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide; at 25 ℃; for 18h; Inert atmosphere;

DOI:10.1039/c8ob00464a

Reference yield: 80.0%

triethylsilyl chloride (994-30-9) + 3-methyl-phenol (108-39-4) → triethyl(3-methylphenoxy)silane (18406-01-4)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃;

DOI:10.1002/chem.201304508

Reference yield:

triethylsilane (617-86-7) + 1-methoxy-3-methyl-benzene (100-84-5) → triethyl(3-methylphenoxy)silane (18406-01-4)

Guidance literature:

With [(η5-pentamethylcyclopentadienyl)Ir(2-phenylpyridine(1-))Cl]; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate; In dichloromethane-d2; at 23 ℃; for 16h; Inert atmosphere; Glovebox; Sealed tube; Irradiation;

DOI:10.1021/acs.organomet.1c00391

upstream raw materials:

triethylsilyl chloride

3-methyl-phenol

triethylsilane

1-methoxy-3-methyl-benzene

Downstream raw materials:

3-methyl-phenol

Refernces

• 1、 Fast, Caleb D.,Schley, Nathan D.. "Light-Promoted Transfer of an Iridium Hydride in Alkyl Ether Cleavage". supporting information. p. 3291 - 3297. Retrieved 2021/10/12.
• 2、 Collins, Karl D.,Ruehling, Andreas,Lied, Fabian,Glorius, Frank. "Rapid assessment of protecting-group stability by using a robustness screen". supporting information. p. 3800 - 3805. Retrieved 2014/04/03.