(+/-)-13-hydroxy-2,3-dimethoxy-10,10-dimethyl-(6ar,14ac)-6a,14a-dihydro-6H,10H-pyrano[2,3-c;5,6-g'] dichromium en-14-one

Base Information

• Chemical Name: (+/-)-13-hydroxy-2,3-dimethoxy-10,10-dimethyl-(6ar,14ac)-6a,14a-dihydro-6H,10H-pyrano[2,3-c;5,6-g'] dichromium en-14-one
• CAS No.: 13122-02-6
• Molecular Formula: C₂₃H₂₂O₇
• Molecular Weight: 410.423
• Mol file: 13122-02-6.mol

Synonyms:(+/-)-13-hydroxy-2,3-dimethoxy-10,10-dimethyl-(6ar,14ac)-6a,14a-dihydro-6H,10H-pyrano[2,3-c;5,6-g'] dichromium en-14-one

Chemical Property of (+/-)-13-hydroxy-2,3-dimethoxy-10,10-dimethyl-(6ar,14ac)-6a,14a-dihydro-6H,10H-pyrano[2,3-c;5,6-g'] dichromium en-14-one

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+/-)-13-hydroxy-2,3-dimethoxy-10,10-dimethyl-(6ar,14ac)-6a,14a-dihydro-6H,10H-pyrano[2,3-c;5,6-g'] dichromium en-14-one

There total 2 articles about (+/-)-13-hydroxy-2,3-dimethoxy-10,10-dimethyl-(6ar,14ac)-6a,14a-dihydro-6H,10H-pyrano[2,3-c;5,6-g'] dichromium en-14-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

alpha-toxicarol (82-09-7) → (+/-)-13-hydroxy-2,3-dimethoxy-10,10-dimethyl-(6ar,14ac)-6a,14a-dihydro-6H,10H-pyrano[2,3-c;5,6-g'] dichromium en-14-one (13122-02-6,82-11-1)

Guidance literature:

Multi-step reaction with 2 steps

1: ethanolic KOH-solution

2: potassium carbonate; acetone

With potassium hydroxide; potassium carbonate; acetone;

Reference yield:

cis-α-toxicarol (13133-20-5) → (+/-)-13-hydroxy-2,3-dimethoxy-10,10-dimethyl-(6ar,14ac)-6a,14a-dihydro-6H,10H-pyrano[2,3-c;5,6-g'] dichromium en-14-one (13122-02-6,82-11-1)

Guidance literature:

With potassium carbonate; acetone;

upstream raw materials:

cis-α-toxicarol

alpha-toxicarol