N,N-dimethyl-4-prop-2-enyl-aniline

Base Information

• Chemical Name: N,N-dimethyl-4-prop-2-enyl-aniline
• CAS No.: 51601-26-4
• Molecular Formula: C11H15 N
• Molecular Weight: 161.247
• Hs Code.: 2921420090
• Mol file: 51601-26-4.mol

Synonyms:Aniline,p-allyl-N,N-dimethyl- (7CI); Benzenamine, N,N-dimethyl-4-(2-propenyl)- (9CI);4-Allyl-N,N-dimethylaniline; N,N-Dimethyl-4-(2-propenyl)benzenamine;N,N-Dimethyl-4-allylaniline; NSC 46438

Chemical Property of N,N-dimethyl-4-prop-2-enyl-aniline

Chemical Property:

• Vapor Pressure: 0.0363mmHg at 25°C
• Boiling Point: 241.3°C at 760 mmHg
• Flash Point: 97.3°C
• PSA: 3.24000
• Density: 0.938g/cm³
• LogP: 2.48110
• Storage Temp.: 2-8°C

Purity/Quality:

98% min ^*data from raw suppliers

3-[(4-N,N-Dimethylamino)phenyl]-1-propene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N-dimethyl-4-prop-2-enyl-aniline

There total 22 articles about N,N-dimethyl-4-prop-2-enyl-aniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

4-(dimethylamino)benzenediazonium tetrafluoroborate (24564-52-1) + acetonitrile (75-05-8,26809-02-9) + allyl-trimethyl-silane (762-72-1) → N'-acetyl-N,N-dimethyl-1,4-phenylenediamine (7463-28-7) + N,N-dimethyl-4-(2-propen-1-yl)benzenamine (51601-26-4) + N,N-dimethyl-aniline (121-69-7,77733-26-7)

Guidance literature:

Irradiation;

DOI:10.1039/b210243a

Reference yield: 84.0%

sodium 1,1-dimethyl-1-(2-propen-1-yl)silanolate (1092390-58-3) + 4-bromo-N,N-dimethylaniline (586-77-6) → N,N-dimethyl-4-(2-propen-1-yl)benzenamine (51601-26-4)

Guidance literature:

With bis(η3-allyl-μ-chloropalladium(II)); In 1,2-dimethoxyethane; at 85 ℃; for 7h; Inert atmosphere;

DOI:10.1021/ja805951j

Reference yield: 81.0%

4-chloro-N,N-dimethylaniline (698-69-1) + allyl-trimethyl-silane (762-72-1) → N,N-dimethyl-4-(2-propen-1-yl)benzenamine (51601-26-4) + N,N-dimethyl-aniline (121-69-7,77733-26-7)

Guidance literature:

In acetonitrile; Irradiation;

DOI:10.1021/jo010469s

upstream raw materials:

allyl bromide

4-dimethylaminophenylmagnesium bromide

bis [4-(N,N-dimethylamino)phenyl] telluride

4-chloro-N,N-dimethylaniline

Downstream raw materials:

(E)-N,N-dimethyl-4-(3-(trimethylsilyl)prop-1-enyl)aniline

(E)-N,N-dimethyl-4-(prop-1-en-1-yl)aniline

Refernces

• 1、 Yang, Bo,Wang, Zhong-Xia. "Nickel-Catalyzed Cross-Coupling of Allyl Alcohols with Aryl- or Alkenylzinc Reagents". . p. 4542 - 4549. Retrieved 2017/05/12.
• 2、 Bagal, Dattatraya B.,Kachkovskyi, Georgiy,Knorn, Matthias,Rawner, Thomas,Bhanage, Bhalchandra M.,Reiser, Oliver. "Trifluoromethylchlorosulfonylation of alkenes: Evidence for an inner-sphere mechanism by a copper phenanthroline photoredox catalyst". supporting information. p. 6999 - 7002. Retrieved 2015/06/08.