N,N'-Bis(2,6-diisopropylphenyl)ethylenediamine

Base Information

• Chemical Name: N,N'-Bis(2,6-diisopropylphenyl)ethylenediamine
• CAS No.: 134030-22-1
• Molecular Formula: C26H40N2
• Molecular Weight: 380.617
• Hs Code.: 2921590090
• European Community (EC) Number: 806-330-9
• DSSTox Substance ID: DTXSID40413079
• Nikkaji Number: J1.444.880B
• Wikidata: Q72445057
• Mol file: 134030-22-1.mol

Synonyms:134030-22-1;N,N'-Bis(2,6-diisopropylphenyl)ethylenediamine;N1,N2-Bis(2,6-diisopropylphenyl)ethane-1,2-diamine;N,N-BIS(2,6-DIISOPROPYLPHENYL)ETHYLENEDIAMINE;N,N'-bis[2,6-di(propan-2-yl)phenyl]ethane-1,2-diamine;MFCD10000903;C26H40N2;SCHEMBL2520538;DTXSID40413079;AKOS015918246;DS-16597;SY224615;BB 0263004;CS-0154309;FT-0603811;A18164;F10259;?N,N'-Bis(2,6-diisopropylphenyl)ethylenediamine;J-006470;N,N'-Bis(2,6-diisopropylphenyl)-1,2-ethanediamine;N,N'-Bis(2,6-diisopropylphenyl)ethylenediamine, 95%;N1,N2-Bis(2,6-diisopropylphenyl)-1,2-ethanediamine;N~1~,N~2~-Bis[2,6-di(propan-2-yl)phenyl]ethane-1,2-diamine;N-(2-(2,6-diisopropylphenylamino)ethyl)-2,6-diisopropylbenzenamine

Chemical Property of N,N'-Bis(2,6-diisopropylphenyl)ethylenediamine

Chemical Property:

• Vapor Pressure: 2.9E-10mmHg at 25°C
• Melting Point: 101-106 °C
• Refractive Index: 1.562
• Boiling Point: 503.5°C at 760 mmHg
• PKA: 4.65±0.50(Predicted)
• Flash Point: 288.9°C
• PSA: 24.06000
• Density: 0.977g/cm³
• LogP: 7.85020
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• XLogP3: 8.1
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 9
• Exact Mass: 380.319149284
• Heavy Atom Count: 28
• Complexity: 356

Purity/Quality:

98% ^*data from raw suppliers

N,N-Bis(2,6-Diisopropylphenyl)ethylenediamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1=C(C(=CC=C1)C(C)C)NCCNC2=C(C=CC=C2C(C)C)C(C)C

Technology Process of N,N'-Bis(2,6-diisopropylphenyl)ethylenediamine

There total 9 articles about N,N'-Bis(2,6-diisopropylphenyl)ethylenediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,2-bis(2,6-diisopropylphenylimino)ethane (74663-75-5,134750-23-5) → N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diamine (134030-22-1)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1021/jo702720a

Reference yield: 91.0%

(1E,2E)-N1,N2-bis(2,6-diisopropylphenyl)-ethane-1,2-diimine (74663-75-5,134750-23-5) → N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diamine (134030-22-1)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 0 - 20 ℃;

DOI:10.1039/b801684d

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) → N,N'-bis(2,6-diisopropylphenyl)ethane-1,2-diamine (134030-22-1)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂O; acetone

In water; acetone;

DOI:10.1021/ol990909q

upstream raw materials:

1,2-bis(2,6-diisopropylphenylimino)ethane

(1E,2E)-N¹,N²-bis(2,6-diisopropylphenyl)-ethane-1,2-diimine

2,6-diisopropylbenzenamine

Glyoxal

Downstream raw materials:

1-(tert-butyl)-1H-benzimidazol-2-amine

Refernces

• 1、 Donohoe, Timothy J.,Harris, Robert M.,Butterworth, Sam,Burrows, Jeremy N.,Cowley, Andrew,Parker, Jeremy S.. "New osmium-based reagent for the dihydroxylation of alkenes". . p. 4481 - 4489. Retrieved 2006.
• 2、 Bestvater, Brian P.,Clarke, Joshua J.,Crudden, Cathleen M.,DeJesus, Joseph F.,Devaraj, Karthik,Eisenberger, Patrick,Kojima, Ryoto. "Hydrosilylation and Mukaiyama aldol-type reaction of quinolines and hydrosilylation of imines catalyzed by a mesoionic carbene-stabilized borenium ion". . p. 6786 - 6791. Retrieved 2021/08/20.
• 3、 Beillard, Audrey,Bantreil, Xavier,Métro, Thomas-Xavier,Martinez, Jean,Lamaty, Frédéric. "Mechanochemistry for facilitated access to N,N-diaryl NHC metal complexes". supporting information. p. 1057 - 1063. Retrieved 2017/02/10.