Ethanol, aluminum salt

Base Information

• Chemical Name: Ethanol, aluminum salt
• CAS No.: 555-75-9
• Deprecated CAS: 112388-36-0,139984-22-8,2835-42-9,82948-46-7,858823-96-8,1091602-92-4,2042146-96-1,2421253-43-0,1091602-92-4,139984-22-8,2835-42-9,82948-46-7
• Molecular Formula: C6H15AlO3
• Molecular Weight: 162.165
• Hs Code.: 2905 19 00
• European Community (EC) Number: 209-105-8
• UNII: S34F5V33DX
• DSSTox Substance ID: DTXSID7027203
• Nikkaji Number: J2.657C
• Wikipedia: Aluminium_triethoxide
• Mol file: 555-75-9.mol

Synonyms:Ethanol, aluminum salt;555-75-9;Triethoxyaluminum;Aluminium triethanolate;ALUMINUM ETHYLATE;aluminum;ethanolate;ALUMINUMETHOXIDE;Ethyl alcohol, aluminum salt;Aluminum triethoxide;UNII-S34F5V33DX;S34F5V33DX;Ethanol, aluminum salt (3:1);HSDB 5430;EINECS 209-105-8;Ethanol, aluminium salt;C2H6O.1/3Al;Ethanol aluminum salt (3:1);aluminum ethanolate;C2-H6-O.1/3Al;aluminum triethylate;aluminium triethoxide;aluminum triethanolate;ALUMINUM ETHOXIDE [MI];TRIS(ETHANOLATO)ALUMINUM;DTXSID7027203;JPUHCPXFQIXLMW-UHFFFAOYSA-N;ALUMINUM TRIETHOXIDE [HSDB];AKOS015841953;A0245

Chemical Property of Ethanol, aluminum salt

Chemical Property:

• Appearance/Colour: white powder
• Vapor Pressure: 0.004Pa at 25℃
• Melting Point: 154-159 °C(lit.)
• Refractive Index: ">
• Boiling Point: 72.6 °C at 760 mmHg
• Flash Point: 8.9 °C
• PSA: 27.69000
• Density: 1.142 g/cm³
• LogP: 1.46160
• Storage Temp.: Store below +30°C.
• Water Solubility.: Soluble in hot xylene, cholorobenzene. Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 162.0836577
• Heavy Atom Count: 10
• Complexity: 2.8

Purity/Quality:

99.9% ^*data from raw suppliers

Aluminum Ethoxide >98.0%(T) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C
• Statements: 11-15-34
• Safety Statements: 8-16-26-36/37/39-43-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metal Alkoxides
• Canonical SMILES: CC[O-].CC[O-].CC[O-].[Al+3]
• Uses: In the reduction of aldehydes and ketones; as catalyst for polymerizations. Aluminum ethoxide is mainly used in industrial settings. It is used as a reducing agent for aldehyde, ketones, polymerization catalyst. Used in the sol-gel process preparation of high purity aluminum sesquioxide. It also used as a reducing reagent, for carbonyl compounds that restore to alcohol.

Technology Process of Ethanol, aluminum salt

There total 26 articles about Ethanol, aluminum salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

(+)589-trans-dichlorobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) (82338-48-5) + triethylaluminum (97-93-8) → (+)589-λ-anti-cis-C2-dichlorobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) (82373-48-6) + aluminum ethoxide (555-75-9)

Guidance literature:

With C₂H₅OH; HCl; In further solvent(s); under N2, Ru complex suspended in Et3Al, mixt. stirred at 75°C for 2 h, mixt. cooled to -10°C, ethanol slowly added, stirred at room temp. for 3.5 h; solvent removed, residue dissolved in CH2Cl2, added concd. HCl, org. layer sepd., dried, recrystd. from CH2Cl2/ethanol;

Reference yield: 89.0%

rac-trans-dichloro((RR,SS)-o-phenylenebis(methylphenylphosphine))ruthenium(II) (82373-45-3) + triethylaluminum (97-93-8) → rac-anti-cis-C2-dichloro((RR,SS)-o-phenylenebis(methylphenylarsine))ruthenium(II) (82442-77-1) + aluminum ethoxide (555-75-9)

Guidance literature:

With C₂H₅OH; HCl; In further solvent(s); under N2, Ru complex suspended in Et3Al, mixt. stirred at 75°C for 2 h, mixt. cooled to -10°C, ethanol slowly added, stirred at room temp. for 3.5 h; solvent removed, residue dissolved in CH2Cl2, added concd. HCl, org. layer sepd., dried, recrystd. from CH2Cl2/ethanol;

Reference yield: 86.0%

meso-trans-dichloro((R,R)-o-phenylenebis(methylphenylphosphine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) (82442-81-7) + triethylaluminum (97-93-8) → rac-cis-C1-dichloro((R,R)-o-phenylenebis(methylphenylarsine))((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II) (82442-78-2) + aluminum ethoxide (555-75-9)

Guidance literature:

With C₂H₅OH; HCl; In further solvent(s); under N2, Ru complex suspended in Et3Al, mixt. stirred at 75°C for 2 h, mixt. cooled to -10°C, ethanol slowly added, stirred at room temp. for 3.5 h; solvent removed, residue dissolved in CH2Cl2, added concd. HCl, org. layer sepd., dried, recrystd. from CH2Cl2/ethanol;

upstream raw materials:

triethyl borate

triethylaluminum

ethanol

sodium ethanolate

Downstream raw materials:

ethyl 3-phenyl-2-propenoate

3-Phenylpropenol

3-phenyl-2-propen-1-yl 3-phenylacrylate

Cinnamic acid

Refernces

• 1、 -. "Method for removing iron impurities in alkoxy aluminum". Paragraph 0038-0040; 0053; 0054. . Retrieved 2019/11/20.
• 2、 -. "Preparation method of aluminum alkoxide". Paragraph 0025; 0026; 0027. . Retrieved 2018/09/08.