2,6,10-Trimethyldodeca-2,6,10-triene

Base Information

• Chemical Name: 2,6,10-Trimethyldodeca-2,6,10-triene
• CAS No.: 7681-88-1
• Molecular Formula: C₁₅H₂₆
• Molecular Weight: 206.371
• Hs Code.: 2901299090
• DSSTox Substance ID: DTXSID00998135
• Wikidata: Q27116874,Q105136505
• Mol file: 7681-88-1.mol

Synonyms:2,6,10-trimethyldodeca-2,6,10-triene;7681-88-1;2,6,10-trimethyl-2,6,10-dodecatriene;DTXSID00998135;AKOS030255143;3,7,11-trimethyl-2,6,10-dodecatriene;NS00122711;Q27116874

Chemical Property of 2,6,10-Trimethyldodeca-2,6,10-triene

Chemical Property:

• PSA: 0.00000
• LogP: 5.42550
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 206.203450829
• Heavy Atom Count: 15
• Complexity: 247

Purity/Quality:

99%, ^*data from raw suppliers

2,6,10-Trimethyl-2,6,10-dodecatriene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=C(C)CCC=C(C)CCC=C(C)C
• Uses: 2,6,10-Trimethyl-2,6,10-dodecatriene is an oligoisoprene and an intermediate in the synthesis of Farnesane (F102380), an antimicrobial agent.

Technology Process of 2,6,10-Trimethyldodeca-2,6,10-triene

There total 5 articles about 2,6,10-Trimethyldodeca-2,6,10-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(+/-)-nerolidol (7212-44-4) + carbon monoxide (201230-82-2) → 2,6,10-trimethyldodeca-2,6,10-triene (7681-88-1) + C16H28O2 + C16H28O2

Guidance literature:

With methoxy(cyclooctadiene)rhodium(I) dimer; hydrogen; triphenylphosphine; In toluene; at 50 ℃; for 24h; under 15201 Torr; Pressure; Reagent/catalyst; Temperature; Time; stereoselective reaction; Autoclave;

DOI:10.1039/c3cy01104f

Reference yield:

(+/-)-nerolidol (7212-44-4) + carbon monoxide (201230-82-2) → 2,6,10-trimethyldodeca-2,6,10-triene (7681-88-1) + C16H28O2 + C16H28O2 + C16H28O2 + C16H28O2

Guidance literature:

With methoxy(cyclooctadiene)rhodium(I) dimer; hydrogen; triphenylphosphine; In toluene; at 50 ℃; for 24h; under 15201 Torr; Pressure; Reagent/catalyst; Temperature; Time; stereoselective reaction; Autoclave;

DOI:10.1039/c3cy01104f

Reference yield:

C18H30O3 → 2,6,10-trimethyldodeca-2,6,10-triene (7681-88-1) + 3,7,11-trimethyl-1,6,10-dodecatriene

Guidance literature:

With bis(cyclopentadienyl)titanium dichloride; manganese; water; triphenylphosphine; palladium dichloride; In tetrahydrofuran; at 20 ℃; for 6h; regioselective reaction; Inert atmosphere;

DOI:10.1002/chem.201003315

upstream raw materials:

nerolidol acetate

(+/-)-nerolidol

carbon monoxide

Refernces

• 1、 -. "OLEFINS AND METHODS FOR MAKING THE SAME". Page/Page column 71-72. . Retrieved 2012/11/06.