2-Furancarboxaldehyde dimethyl acetal

Base Information

• Chemical Name: 2-Furancarboxaldehyde dimethyl acetal
• CAS No.: 1453-62-9
• Molecular Formula: C7H10O3
• Molecular Weight: 142.155
• Mol file: 1453-62-9.mol

Synonyms:2-(Dimethoxymethyl)furan;2-Furancarboxaldehydedimethyl acetal;Furfural dimethyl acetal;

Chemical Property of 2-Furancarboxaldehyde dimethyl acetal

Chemical Property:

• Appearance/Colour: Light-colour to yellow clear liquid or solid
• Vapor Pressure: 26.3mmHg at 25°C
• Refractive Index: 1.449
• Boiling Point: 111.8 °C at 760 mmHg
• Flash Point: 22.7 °C
• PSA: 31.60000
• Density: 1.052 g/cm³
• LogP: 1.57100

Purity/Quality:

98%Min ^*data from raw suppliers

2-(Dimethoxymethyl)furan 99%min ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Furancarboxaldehyde dimethyl acetal

There total 10 articles about 2-Furancarboxaldehyde dimethyl acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

furfural (98-01-1) → Tetrahydrofurfuryl alcohol (97-99-4) + (2-furyl)methyl alcohol (98-00-0,25212-86-6,93793-62-5) + 2-furaldehyde dimethyl acetal (1453-62-9)

Guidance literature:

With hydrogen; In methanol; at 100 ℃; under 15001.5 Torr; Reagent/catalyst; Catalytic behavior; Autoclave;

DOI:10.1016/j.catcom.2020.106221

Reference yield: 32.0%

methanol (67-56-1) + D-Xylose (87-72-9,608-45-7,608-46-8,608-47-9,2460-44-8,6748-95-4,6763-34-4,7261-26-9,7283-06-9,7283-07-0,7296-55-1,7296-56-2,7296-58-4,7296-59-5,7296-60-8,7296-61-9,7296-62-0,7322-30-7,10257-31-5,10257-32-6,10257-33-7,10257-34-8,10257-35-9,19982-83-3,20242-88-0,28697-53-2,36562-42-2,41546-41-2,89299-64-9,107655-34-5,115794-06-4,115794-07-5,130550-15-1,130606-21-2) → furfural (98-01-1) + 2-furaldehyde dimethyl acetal (1453-62-9) + methyl xyloside (91-09-8,612-05-5,1825-00-9,2500-78-9,3867-83-2,3945-28-6,5328-63-2,6206-67-3,6207-01-8,6207-03-0,7404-24-2,17289-61-1,18449-76-8,33509-64-7,36793-06-3,41897-31-8,41897-32-9,41897-33-0,41897-34-1,41897-37-4,41897-38-5,41897-39-6,53448-52-5,65137-86-2,89615-04-3,89615-05-4,131233-91-5,14703-09-4) + 2,2-dimethoxyethanol (30934-97-5) + methyl lactate (547-64-8,2155-30-8) + trans-2,5-dihydroxy-3-pentenoic acid methyl ester

Guidance literature:

With Sn-beta zeolite; at 160 ℃; for 2h; Microwave irradiation;

DOI:10.1039/c6ra26708d

Reference yield: 23.0%

methanol (67-56-1) + D-Xylose (87-72-9,608-45-7,608-46-8,608-47-9,2460-44-8,6748-95-4,6763-34-4,7261-26-9,7283-06-9,7283-07-0,7296-55-1,7296-56-2,7296-58-4,7296-59-5,7296-60-8,7296-61-9,7296-62-0,7322-30-7,10257-31-5,10257-32-6,10257-33-7,10257-34-8,10257-35-9,19982-83-3,20242-88-0,28697-53-2,36562-42-2,41546-41-2,89299-64-9,107655-34-5,115794-06-4,115794-07-5,130550-15-1,130606-21-2) → furfural (98-01-1) + 2-furaldehyde dimethyl acetal (1453-62-9) + methyl xyloside (91-09-8,612-05-5,1825-00-9,2500-78-9,3867-83-2,3945-28-6,5328-63-2,6206-67-3,6207-01-8,6207-03-0,7404-24-2,17289-61-1,18449-76-8,33509-64-7,36793-06-3,41897-31-8,41897-32-9,41897-33-0,41897-34-1,41897-37-4,41897-38-5,41897-39-6,53448-52-5,65137-86-2,89615-04-3,89615-05-4,131233-91-5,14703-09-4) + methyl lactate (547-64-8,2155-30-8) + trans-2,5-dihydroxy-3-pentenoic acid methyl ester + 3-hydroxy-5-hydroxymethyl-dihydro-furan-2-one (74243-47-3)

Guidance literature:

With Sn-beta zeolite; at 160 ℃; for 2h; Temperature; Microwave irradiation;

DOI:10.1039/c6ra26708d

upstream raw materials:

D-xylose

methanol

D-xylose

β-D-xylopyranoside

Downstream raw materials:

1-dimethoxymethyl-3-endo-hydroxy-2-endo-<(E)-1'-styryl>-8-oxabicyclo<3.2.1>oct-6-ene

N-(furan-2-yl(methoxy)methyl)-N-(4-methoxyphenyl)acetamide

(1S,3S,4S,5S)-3-Dimethoxymethyl-8-iodo-4-((E)-styryl)-2,6-dioxa-tricyclo[3.3.1.0^3,7]nonane

1-(dimethoxymethyl)-2-(2-phenylethenyl)-8-oxabicyclo<3.2.1>oct-6-en-3-ol

Refernces

• 1、 Weerachawanasak, Patcharaporn,Krawmanee, Pacharaporn,Inkamhaeng, Weerachat,Cadete Santos Aires, Francisco J.,Sooknoi, Tawan,Panpranot, Joongjai. "Development of bimetallic Ni-Cu/SiO2 catalysts for liquid phase selective hydrogenation of furfural to furfuryl alcohol". . . Retrieved 2021.
• 2、 Cadete Santos Aires, Francisco José,Khruechao, Kitima,Mekasuwandumrong, Okorn,Panpranot, Joongjai,Pongthawornsakun, Boontida,Tolek, Weerachon,Weerachawanasak, Patcharaporn. "Flame spray-synthesized Pt-Co/TiO2 catalysts for the selective hydrogenation of furfural to furfuryl alcohol". . . Retrieved 2021.