B-(9,10-Diphenyl-2-anthracenyl)boronic acid

Base Information

• Chemical Name: B-(9,10-Diphenyl-2-anthracenyl)boronic acid
• CAS No.: 597553-98-5
• Molecular Formula: C26H19BO2
• Molecular Weight: 374.247
• Mol file: 597553-98-5.mol

Synonyms:B-(9,10-Diphenyl-2-anthracenyl)boronic acid

Chemical Property of B-(9,10-Diphenyl-2-anthracenyl)boronic acid

Chemical Property:

• Boiling Point: 569.6 °C at 760 mmHg
• PKA: 8.45±0.30(Predicted)
• Flash Point: 298.3 °C
• PSA: 40.46000
• Density: 1.28 g/cm³
• LogP: 5.00680
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

99% ^*data from raw suppliers

9,10-Diphenylanthracene-2-boronic Acid (contains varying amounts of Anhydride) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of B-(9,10-Diphenyl-2-anthracenyl)boronic acid

There total 12 articles about B-(9,10-Diphenyl-2-anthracenyl)boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

Triisopropyl borate (5419-55-6) + 2-bromo-9,10-diphenylanthracene (201731-79-5) → (9,10-diphenylanthracene-2-yl)boronic acid (597553-98-5)

Guidance literature:

2-bromo-9,10-diphenylanthracene; With n-butyllithium; In tetrahydrofuran; for 0.25h;

Triisopropyl borate; In tetrahydrofuran;

Reference yield: 80.0%

2-bromo-9,10-diphenylanthracene (201731-79-5) → (9,10-diphenylanthracene-2-yl)boronic acid (597553-98-5)

Guidance literature:

2-bromo-9,10-diphenylanthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h;

With Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 3h;

With hydrogenchloride; In tetrahydrofuran; hexane; water; for 1h;

Reference yield: 80.0%

Trimethyl borate (121-43-7,63156-11-6) → (9,10-diphenylanthracene-2-yl)boronic acid (597553-98-5)

Guidance literature:

2-bromo-9,10-diphenylanthracene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; for 1h;

Trimethyl borate; In tetrahydrofuran; hexane; at -78 - 20 ℃; for 3h;

With hydrogenchloride; water; In tetrahydrofuran; hexane; for 1h;

upstream raw materials:

Trimethyl borate

2-bromo-9,10-diphenylanthracene

phenyllithium

triethyl borate

Downstream raw materials:

C₃₉H₂₆N₂

C₄₀H₂₈N₂

2-(2-nitrophenyl)-9,10-diphenylanthracene

6,11-diphenyl-13H-13-azaindeno[1,2-b]anthracene

Refernces

• 1、 -. "Nitrogen-containing heterocyclic derivative and application of nitrogen-containing heterocyclic derivative to organic electroluminescence device". Paragraph 0045. . Retrieved 2017/05/02.
• 2、 -. "CONDENSED-CYCLIC COMPOUND AND ORGANIC LIGHT EMITTING DIODE HAVING ORGANIC LAYER INCLUDING THE SAME". . . Retrieved 2011/02/26.