Bis(4-methylphenyl)chlorophosphine

Base Information Edit

Chemical Name:Bis(4-methylphenyl)chlorophosphine
CAS No.:1019-71-2
Molecular Formula:C14H14ClP
Molecular Weight:248.692
Hs Code.:2903999090
European Community (EC) Number:624-496-9
DSSTox Substance ID:DTXSID70400533
Nikkaji Number:J1.877.808D
Wikidata:Q72446469
Mol file:1019-71-2.mol

Synonyms:1019-71-2;BIS(4-METHYLPHENYL)CHLOROPHOSPHINE;Chlorodi-p-tolylphosphine;Chlorodi(p-tolyl)phosphine;Chloro-bis(4-methylphenyl)phosphane;Bis(4-methylphenyl)phosphinous chloride;13685-23-9;P,P-Bis(4-methylphenyl)-phosphinous chloride;chlorobis(4-methylphenyl)phosphine;Chlorodi(p-tolyl)phosphine, 95per cent;Bis(p-tolyl)chlorophosphine;di-p-tolylchlorophosphine;Chlorodi-p-tolylphosphane;Phosphinous chloride, P,P-bis(4-methylphenyl)-;SCHEMBL667708;Di(p-tolyl)phosphinous Chloride;DTXSID70400533;BJBXRRHIBSXGLF-UHFFFAOYSA-N;chlorobis(4-methylphenyl)phosphane;Chlorodi(p-tolyl)phosphine, 95%;AMY42231;BAA01971;BIS-(P-TOLYL)CHLOROPHOSPHINE;MFCD01630844;AKOS015900113;Bis(4-methylphenyl)chlorophosphine, 96%;C3201;CS-0182673;FT-0753124;F16265;A855247

Suppliers and Price of Bis(4-methylphenyl)chlorophosphine

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Chlorodi(p-tolyl)phosphine
500mg
$ 240.00

TCI Chemical
Chlorodi(p-tolyl)phosphine >98.0%(T)
1g
$ 114.00

Sigma-Aldrich
Bis(4-methylphenyl)chlorophosphine 96%
250mg
$ 42.20

Sigma-Aldrich
Bis(4-methylphenyl)chlorophosphine 96%
1g
$ 155.00

Crysdot
Chlorodi-p-tolylphosphine 97%
5g
$ 291.00

Crysdot
Chlorodi-p-tolylphosphine 97%
1g
$ 97.00

Arctom
Chlorodi-p-tolylphosphine 98%
1g
$ 112.00

Arctom
Chlorodi-p-tolylphosphine 98%
250mg
$ 41.00

Arctom
Chlorodi-p-tolylphosphine 98%
5g
$ 259.00

American Custom Chemicals Corporation
CHLORO-BIS-(4-METHYLPHENYL)PHOSPHANE 95.00%
5MG
$ 455.39

Total 62 raw suppliers

Chemical Property of Bis(4-methylphenyl)chlorophosphine Edit

Chemical Property:

Vapor Pressure:0.000112mmHg at 25°C
Refractive Index:n20/D1.501
Boiling Point:346.9 °C at 760 mmHg
Flash Point:163.6 °C
PSA：13.59000
Density:1.1 g/mL at 25 °C
LogP:3.88990
Storage Temp.:2-8°C
Sensitive.:Air & Moisture Sensitive
Water Solubility.:Reacts with water.
XLogP3:4.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:2
Exact Mass:248.0521651
Heavy Atom Count:16
Complexity:181

Purity/Quality:

98% ^*data from raw suppliers

Chlorodi(p-tolyl)phosphine ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 14-34
Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)Cl
Uses Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions. Reactant for synthesis of:Palladium catalysts for C-C bond forming cross-coupling reactionsLigands for nickel(0)-catalyzed isomerization reactionsPhosphinosulfonamide nickel complexes for oligomerization reactionsReactant for:Pd-catalyzed intramolecular asymmetric allylic amination and ring-closing metathesisPhosphinylation reactions

Technology Process of Bis(4-methylphenyl)chlorophosphine

There total 10 articles about Bis(4-methylphenyl)chlorophosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%