1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene

Base Information

• Chemical Name: 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene
• CAS No.: 174063-87-7
• Molecular Formula: C33H32O10
• Molecular Weight: 588.611
• Hs Code.: 2917399590
• Mol file: 174063-87-7.mol

Synonyms:4-(3-Acryloyloxypropyloxy)-benzoesure 2-methyl-1, 4-phenylester;2-Methylbenzene-1,4-diyl bis{4-[3-(acryloyloxy)propoxy]benzoate};

Chemical Property of 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene

Chemical Property:

• Vapor Pressure: 0.003Pa at 25℃
• Boiling Point: 733.5 °C at 760 mmHg
• Flash Point: 303.9 °C
• PSA: 123.66000
• Density: 1.219 g/cm³
• LogP: 5.42960
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Water Solubility.: 5.3μg/L at 20℃

Purity/Quality:

2-Methyl-1,4-phenylene bis{4-[3-(acryloyloxy)propoxy]benzoate} ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene

There total 3 articles about 1,4-Bis-[4-(3-acryloyloxypropyloxy)benzoyloxy]-2-methylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-(3-acryloyloxypropyloxy)benzoic acid (245349-46-6) + 2-methylbenzene-1,4-diol (95-71-6,96937-50-7) → 2-methylbenzene-1,4-diyl bis{4-[3-(acryloyloxy)propoxy]benzoate} (174063-87-7)

Guidance literature:

4-(3-acryloyloxypropyloxy)benzoic acid; With methanesulfonyl chloride; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; ethyl acetate; for 1h; Cooling with ice;

2-methylbenzene-1,4-diol; With 1-methyl-1H-imidazole; triethylamine; In tetrahydrofuran; ethyl acetate; at 20 ℃; for 2h; Cooling with ice;

Reference yield:

2-methylbenzene-1,4-diol (95-71-6,96937-50-7) + C14H16O7S → 2-methylbenzene-1,4-diyl bis{4-[3-(acryloyloxy)propoxy]benzoate} (174063-87-7)

Guidance literature:

With dmap; triethylamine; In tetrahydrofuran; for 1h; Cooling with ice;

Reference yield:

4-(3-acryloyloxypropyloxy)benzoic acid (245349-46-6) → 2-methylbenzene-1,4-diyl bis{4-[3-(acryloyloxy)propoxy]benzoate} (174063-87-7)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / tetrahydrofuran / 0.5 h / Cooling with ice

2: triethylamine; dmap / tetrahydrofuran / 1 h / Cooling with ice

With dmap; triethylamine; In tetrahydrofuran;

upstream raw materials:

4-(3-acryloyloxypropyloxy)benzoic acid

2-methylbenzene-1,4-diol

Refernces

• 1、 -. "Compound". Paragraph 0054; 0060; 0062. . Retrieved 2016/12/01.