4-Styryltriphenylamine

Base Information

• Chemical Name: 4-Styryltriphenylamine
• CAS No.: 89114-74-9
• Molecular Formula: C₂₆H₂₁N
• Molecular Weight: 347.459
• European Community (EC) Number: 811-140-4
• Nikkaji Number: J1.710.956A,J2.037.625B
• Mol file: 89114-74-9.mol

Synonyms:4-Styryltriphenylamine;89114-74-9;(E)-N,N-Diphenyl-4-styrylaniline;406729-10-0;starbld0007073;SCHEMBL133151;DXYYLUGHPCHMRQ-WUKNDPDISA-N;benzenamine, N,N-diphenyl-4-[2-phenylethenyl]-

Chemical Property of 4-Styryltriphenylamine

Chemical Property:

• Melting Point: 151.0 to 155.0 °C
• Boiling Point: 510.281 °C at 760 mmHg
• Flash Point: 227.428 °C
• PSA: 3.24000
• Density: 1.144 g/cm³
• LogP: 7.32680
• Solubility.: soluble in Toluene
• XLogP3: 7.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 5
• Exact Mass: 347.167399674
• Heavy Atom Count: 27
• Complexity: 411

Purity/Quality:

98%,99%, ^*data from raw suppliers

4-Styryltriphenylamine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C=CC2=CC=C(C=C2)N(C3=CC=CC=C3)C4=CC=CC=C4
• Isomeric SMILES: C1=CC=C(C=C1)/C=C/C2=CC=C(C=C2)N(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of 4-Styryltriphenylamine

There total 19 articles about 4-Styryltriphenylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

→ 4-styryl-triphenylamine (89114-74-9)

Guidance literature:

With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate; Glovebox; Inert atmosphere;

With cyclo-octa-1,5-diene; for 1.65h; Inert atmosphere;

Reference yield: 94.0%

iodobenzene (591-50-4) + 4-vinyl benzylamine (1520-21-4,25086-42-4) → N,N-diphenyl-4-(2-phenylethenyl)benzenamine (406729-10-0,89114-74-9)

Guidance literature:

With sodium t-butanolate; 2,8,9-tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; at 100 ℃; for 24h;

DOI:10.1002/anie.200462938

Reference yield: 92.0%

bromobenzene (108-86-1,52753-63-6) + 4-vinyl benzylamine (1520-21-4,25086-42-4) → N,N-diphenyl-N-(4-vinylphenyl)amine (25069-74-3) + N,N-diphenyl-4-(2-phenylethenyl)benzenamine (406729-10-0,89114-74-9)

Guidance literature:

With sodium t-butanolate; 2,8,9-tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In toluene; at 100 ℃; for 12h;

DOI:10.1002/anie.200462938

upstream raw materials:

N,N-diphenyl-4-(2-phenylethenyl)benzenamine

(E)-4-bromostilbene

diphenylamine

styrene

Refernces

• 1、 Kumari, Beena,Singh, Amit,Jana, Palash,Radhakrishna, Mithun,Kanvah, Sriram. "White light emission in water through admixtures of donor-π-acceptor siblings: Experiment and simulation". . p. 11701 - 11709. Retrieved 2019/07/31.
• 2、 Lin, Cheng-Kai,Prabhakar,Yang, Jye-Shane. "O -amino conjugation effect on the photochemistry of trans -aminostilbenes". scheme or table. p. 3233 - 3242. Retrieved 2011/06/10.