2-Methyl 6-methylene 2-octene

Base Information

• Chemical Name: 2-Methyl 6-methylene 2-octene
• CAS No.: 10054-09-8
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• DSSTox Substance ID: DTXSID00333709
• Nikkaji Number: J1.878.871C
• Metabolomics Workbench ID: 5204
• Mol file: 10054-09-8.mol

Synonyms:2-Methyl 6-methylene 2-octene;10054-09-8;2-methyl-6-methylideneoct-2-ene;2-Octene, 2-methyl-6-methylene-;2-methyl-6-methyleneoct-2-ene;2-Methyl-6-methylene-2-octene;DTXSID00333709;LMFA11000506;2-Ethyl-6-methyl-1,5-heptadiene #

Chemical Property of 2-Methyl 6-methylene 2-octene

Chemical Property:

• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 4
• Exact Mass: 138.140850574
• Heavy Atom Count: 10
• Complexity: 125

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(=C)CCC=C(C)C

Technology Process of 2-Methyl 6-methylene 2-octene

There total 2 articles about 2-Methyl 6-methylene 2-octene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

7-methyl-3-methene-1,6-octadiene (123-35-3) → dihydromyrcene (2436-90-0) + 2,6-dimethylocta-2(Z),6-diene (2492-22-0) + (E)-3,7-dimethyl-2,6-octadien (2609-23-6) + 2-ethyl-6-methyl-1,5-heptadiene (10054-09-8)

Guidance literature:

With hydrogen; ; In 1,2-dimethoxyethane; at 17 ℃; under 760 Torr; Product distribution; Mechanism; rate of H₂ uptake;;

DOI:10.1246/bcsj.58.16

Reference yield:

7-methyl-3-methene-1,6-octadiene (123-35-3) → 2,6-dimethyl-oct-2-ene (4057-42-5) + dihydromyrcene (2436-90-0) + 2,6-dimethylocta-2(Z),6-diene (2492-22-0) + (E)-3,7-dimethyl-2,6-octadien (2609-23-6) + 2-ethyl-6-methyl-1,5-heptadiene (10054-09-8)

Guidance literature:

With hydrogen; at 74.84 ℃; for 0.3h; under 4560.31 Torr; Reagent/catalyst; Temperature; Pressure;

DOI:10.1039/c2ta00199c

Reference yield:

2-ethyl-6-methyl-1,5-heptadiene (10054-09-8) + P,P-diphenyl-N-(phenylmethylene)phosphinic amide (98837-46-8,67764-52-7) + bis(pinacol)diborane (73183-34-3) → C35H45BNO3P

Guidance literature:

bis(pinacol)diborane; With 2,2'-bis[di(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl; potassium methanolate; copper (I) acetate; In toluene; at 0 ℃; Inert atmosphere; Glovebox; Schlenk technique;

2-ethyl-6-methyl-1,5-heptadiene; P,P-diphenyl-N-(phenylmethylene)phosphinic amide; In toluene; at 0 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.201607493

upstream raw materials:

7-methyl-3-methene-1,6-octadiene

Refernces

• 1、 Dahlén, Anders,Hilmersson, G?ran. "Selective reduction of carbon-carbon double and triple bonds in conjugated olefins mediated by SmI2/H2O/amine in THF". . p. 2661 - 2664. Retrieved 2007/10/03.