methyltris(2,6-diisopropylphenolato)titanium

Base Information

• Chemical Name: methyltris(2,6-diisopropylphenolato)titanium
• CAS No.: 1303613-03-7
• Molecular Formula: C₃₇H₅₄O₃Ti
• Molecular Weight: 594.714
• Mol file: 1303613-03-7.mol

Synonyms:

Chemical Property of methyltris(2,6-diisopropylphenolato)titanium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyltris(2,6-diisopropylphenolato)titanium

There total 1 articles about methyltris(2,6-diisopropylphenolato)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

tris(2,6-diisopropylphenolato)titanium(IV) chloride (151041-52-0) + methyllithium (917-54-4) → methyltris(2,6-diisopropylphenolato)titanium (1303613-03-7)

Guidance literature:

In diethyl ether; byproducts: LiCl; N2, a soln. of Li compd. added to a soln. of Ti compd. at -78°C, allowed to warm to ambient temp., stirred for 2 h; solvent removed (vac.), treated (hexane), filtered, concd. (vac.), stored at -30°C for a few d; elem. anal.;

DOI:10.1002/ejic.201001108

Reference yield:

K(1+)*H2B(C5H10)(1-)=K[H2B(C5H10)] (201806-11-3) + methyltris(2,6-diisopropylphenolato)titanium (1303613-03-7) → tetrakis(2,6-diisopropylphenolato)titanium

Guidance literature:

In pentane; byproducts: KCl; N2, a soln. of Ti compd. slowly added to a soln. of B compd. (-100.degre.C), warmed to room temp. (3 h), stirred for 30 min; filtered, concd., stored at -30°C. for 3 wk; XRD;

DOI:10.1002/ejic.201001108

Reference yield:

9-borabicyclo-[3.3.1]nonane dimer + methyltris(2,6-diisopropylphenolato)titanium (1303613-03-7) → 9-(2,6-diisopropylphenolato)-9-borabicyclononane + 9-methyl-9-borabicyclo[3.3.1]nonane (23418-81-7)

Guidance literature:

In diethyl ether; for 1h; Inert atmosphere;

DOI:10.1002/ejic.201001108

upstream raw materials:

tris(2,6-diisopropylphenolato)titanium(IV) chloride

methyllithium

Downstream raw materials:

9-methyl-9-borabicyclo[3.3.1]nonane

9-(2,6-diisopropylphenolato)-9-borabicyclononane

9-methyl-9-borabicyclo[3.3.1]nonane

diborane

Refernces