C₆₀H₄₈N₁₆O₄Zn

Base Information

• Chemical Name: C₆₀H₄₈N₁₆O₄Zn
• CAS No.: 1259925-68-2
• Molecular Formula: C₆₀H₄₈N₁₆O₄Zn
• Molecular Weight: 1122.54
• Mol file: 1259925-68-2.mol

Synonyms:

Chemical Property of C₆₀H₄₈N₁₆O₄Zn

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of C₆₀H₄₈N₁₆O₄Zn

There total 3 articles about C₆₀H₄₈N₁₆O₄Zn which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

5-(2-isopropylphenoxy)pyrazine-2,3-dicarbonitrile (1259925-60-4) → C60H48N16O4Zn (1259925-68-2)

Guidance literature:

With quinoline; zinc(II) chloride bisquinoline complex; at 170 - 175 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.poly.2010.08.036

Reference yield: 42.0%

zinc(II) chloride bisquinoline complex (14318-73-1) + 5-(2-isopropylphenoxy)pyrazine-2,3-dicarbonitrile → [tetra(2-isopropylphenoxy)-(octazaphthalocyaninato)]zinc(II) (1259925-68-2)

Guidance literature:

With quinoline; In neat (no solvent); (N2); dicarbonitrile, zinc complex and quinoline were stirred for 15 minat ambient temp., heated at 170-175°C for 2 h; sonicated with Et2O, collected solid was stirred with MeOH for 1 h at ambient temp., solid was dissolved in CH2Cl2, column chromy. (silica, MeCN), dried at 0.5 mm Hg at ambient temp.;

DOI:10.1016/j.poly.2010.08.036

Reference yield:

2-(1-methylethyl)phenol (88-69-7) + 5-chloropyrazine-2,3-dicarbonitrile (72111-57-0) → C60H48N16O4Zn (1259925-68-2)

Guidance literature:

Multi-step reaction with 2 steps

1: triethylamine / acetone / 2 h / 20 °C

2: quinoline; zinc(II) chloride bisquinoline complex / 2 h / 170 - 175 °C / Inert atmosphere

With quinoline; zinc(II) chloride bisquinoline complex; triethylamine; In acetone;

DOI:10.1016/j.poly.2010.08.036

upstream raw materials:

zinc(II) chloride bisquinoline complex

5-(2-isopropylphenoxy)pyrazine-2,3-dicarbonitrile

2-(1-methylethyl)phenol

5-chloropyrazine-2,3-dicarbonitrile

Refernces