(Ph3P)PdCl(η(2)-N,O-NH2CH(2-thienyl)COO)

Base Information

• Chemical Name: (Ph3P)PdCl(η(2)-N,O-NH2CH(2-thienyl)COO)
• CAS No.: 416879-89-5
• Molecular Formula: C₂₄H₂₁ClNO₂PPdS
• Molecular Weight: 560.349
• Mol file: 416879-89-5.mol

Synonyms:

Chemical Property of (Ph3P)PdCl(η(2)-N,O-NH2CH(2-thienyl)COO)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (Ph3P)PdCl(η(2)-N,O-NH2CH(2-thienyl)COO)

There total 1 articles about (Ph3P)PdCl(η(2)-N,O-NH2CH(2-thienyl)COO) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

D,L-(2-thienyl)glycine (21124-40-3,4052-59-9) + [PdCl2(triphenylphosphine)]2 → (Ph3P)PdCl(η(2)-N,O-NH2CH(2-thienyl)COO) (416879-89-5,416848-17-4)

Guidance literature:

With sodium methylate; In methanol; dichloromethane; byproducts: NaCl; equimolar amt. of soln. of NaOMe in MeOH added to suspn. of amino acid in MeOH, stirred at room temp. for 0.5 h, soln. added to soln. of equimolar amt. of Pd complex in CH2Cl2, stirred at room temp. for 3 h; solvent evapd. in vac., residue extd. with CH2Cl2 several times, combined extracts filtered through Celite, concd., dropwise addn. to n-pentane,centrifuged, ppt. washed with n-pentane, dried in vac.; elem. anal.;

DOI:10.1515/znb-2001-1204

upstream raw materials:

D,L-(2-thienyl)glycine

Refernces