C₆H₅NC(CH₃)CHC(CH₃)NC₆H₅AlI₂

Base Information

• Chemical Name: C₆H₅NC(CH₃)CHC(CH₃)NC₆H₅AlI₂
• CAS No.: 420087-18-9
• Molecular Formula: C₁₇H₁₇AlI₂N₂
• Molecular Weight: 530.126
• Mol file: 420087-18-9.mol

Synonyms:

Chemical Property of C₆H₅NC(CH₃)CHC(CH₃)NC₆H₅AlI₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of C₆H₅NC(CH₃)CHC(CH₃)NC₆H₅AlI₂

There total 2 articles about C₆H₅NC(CH₃)CHC(CH₃)NC₆H₅AlI₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

CH3NC(CH3)CHC(CH3)N(CH3)AlH2 (281654-50-0) + aluminium(III) iodide (7784-23-8) → C6H5NC(CH3)CHC(CH3)NC6H5AlI2 (420087-18-9)

Guidance literature:

In dichloromethane; under inert gas, 2 equiv. of Me3NHI was added to CH2Cl2 soln. of Al-complex at -20 °C., stirring for 3 h, warming up to room temp., stirring at room temp. for 8 h; solvent was removed in vac., residue was three times extd. with toluene,solvent was removed, solid was recrystd. from toluene/pentane at -30 .d egree.C, elem. anal.;

DOI:10.1002/1521-3749(200202)628:2<458::AID-ZAAC458>3.0.CO;2-N

Reference yield: 47.0%

(Ph2-nacnac)AlH2 (281654-52-2) + trimethylammonium iodide (20230-89-1) → C6H5NC(CH3)CHC(CH3)NC6H5AlI2 (420087-18-9)

Guidance literature:

In dichloromethane; under inert atm., excess of Me3NHI, 0 °C, stirring for 24 h and another 24 h at 10 °C; mixt. was evapd. in vac., residue was extd. with toluene/CH2Cl2 (8:2), solid was recrystd. from toluene/CH2Cl2 at -30 °C, elem. anal.;

DOI:10.1002/1521-3749(200202)628:2<458::AID-ZAAC458>3.0.CO;2-N

upstream raw materials:

CH₃NC(CH₃)CHC(CH₃)N(CH₃)AlH₂

aluminium(III) iodide

(Ph₂-nacnac)AlH₂

trimethylammonium iodide

Refernces