Tristannane, octabutyl-

Base Information

• Chemical Name: Tristannane, octabutyl-
• CAS No.: 1066-68-8
• Molecular Formula: C32H72Sn3
• Molecular Weight: 813.054
• Mol file: 1066-68-8.mol

Synonyms:

Chemical Property of Tristannane, octabutyl-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Tristannane, octabutyl-

There total 2 articles about Tristannane, octabutyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

bis(tri-n-butyltin)oxide (56-35-9) → dodeca-n-butylpentatin (104493-08-5) + bis(tri-n-butyltin) (813-19-4) + tetra-n-butyltin(IV) (1461-25-2) + deca-n-butyltetratin (3902-99-6) + (n-Bu)3Sn[(n-Bu)2Sn]Sn(n-Bu)3 (1066-68-8)

Guidance literature:

With formic acid; In not given; byproducts: CO2, H2O; 100°C, stirring (4 h), then 200°C (200 Torr, 4 h), addn. of further formic acid, then 100°C (30 min); further product: Bu3SnOCHO; cooling to room temp., addn. of MeOH, decantation, addn. of petroleum ether, filtration, evapn., distn.; mixt. of products detd. by (119)Sn-NMRspectroscopy and liquid chromy.;

DOI:10.1016/0022-328X(85)87458-1

Reference yield:

dibutylstannane (1002-53-5) → tri-n-butyl-tin hydride (688-73-3) + bis(tri-n-butyltin) (813-19-4) + deca-n-butyltetratin (3902-99-6) + (n-Bu)3Sn[(n-Bu)2Sn]Sn(n-Bu)3 (1066-68-8)

Guidance literature:

In neat (no solvent); byproducts: H2; (N2), Schlenk techniques; heating Sn compd. (200°C) for 6 h; NMR;

DOI:10.1139/V10-130

upstream raw materials:

bis(tri-n-butyltin)oxide

dibutylstannane

Refernces

• 1、 Jousseaume, Bernard,Chanson, Evelyne,Bevilacqua, Marcel,Saux, Annie,Pereyre, Michel,et al.. "A NEW PREPARATION OF HEXAALKYLDITINS. 119Sn NMR AND CHROMATOGRAPHIC DATA ON LINEAR POLYTINS". . p. C41 - C45. Retrieved 2007/10/02.