NiFe(1,2-ethanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3

Base Information

• Chemical Name: NiFe(1,2-ethanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3
• CAS No.: 1332326-94-9
• Molecular Formula: C₃₁H₅₂FeNiO₃P₂S₂
• Molecular Weight: 713.369
• Mol file: 1332326-94-9.mol

Synonyms:

Chemical Property of NiFe(1,2-ethanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of NiFe(1,2-ethanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3

There total 2 articles about NiFe(1,2-ethanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(1,2-bis(dicyclohexylphosphino)ethane)dichloronickel(II)] (96555-88-3) → NiFe(1,2-ethanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3 (1332326-94-9)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N / dichloromethane

2: (C₅H₅)2Co / dichloromethane

With Et₃N; (C₅H₅)2Co; In dichloromethane;

DOI:10.1021/ic2012759

Reference yield:

diiodotetracarbonyliron(II) (15616-56-5,14911-55-8,14878-30-9) + Ni(1,2-ethanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)*CH2Cl2*2(hexane) → NiFe(1,2-ethanedithiolate)(1,2-bis(dicyclohexylphosphino)ethane)(CO)3 (1332326-94-9)

Guidance literature:

With (C₅H₅)2Co; In dichloromethane; using Schlenk techniques; CH2Cl2 added to mixt. of Fe complex and Ni complex at room temp.; stirred at room temp. for 15 min; treated with (C5H5)2Co; stirred for 30 min; evapd. under reduced pressure; washed with MeCN; filtered through silicagel pad (CH2Cl2); CH2Cl2 soln. concd. to dryness under vac.;

DOI:10.1021/ic2012759

upstream raw materials:

diiodotetracarbonyliron(II)

[(1,2-bis(dicyclohexylphosphino)ethane)dichloronickel(II)]

Refernces