Technology Process of C29H39P
There total 3 articles about C29H39P which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
9-butyl-9H-fluorene;
With
n-butyllithium;
In
hexane; tert-butyl methyl ether;
at 0 - 20 ℃;
for 2.25h;
Inert atmosphere;
chlorodicyclohexylphosphane;
In
hexane; tert-butyl methyl ether;
at -30 - 20 ℃;
for 1.25h;
Inert atmosphere;
DOI:10.1021/op7001479
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: potassium tert-butylate / 5,5-dimethyl-1,3-cyclohexadiene / 0.08 h / Inert atmosphere; Reflux
1.2: 0.17 h / 25 °C / Inert atmosphere; Reflux
2.1: hydrogen; palladium 10% on activated carbon / 20 °C / 7500.75 Torr
3.1: n-butyllithium / tert-butyl methyl ether; hexane / 2.25 h / 0 - 20 °C / Inert atmosphere
3.2: 1.25 h / -30 - 20 °C / Inert atmosphere
With
n-butyllithium; palladium 10% on activated carbon; potassium tert-butylate; hydrogen;
In
5,5-dimethyl-1,3-cyclohexadiene; hexane; tert-butyl methyl ether;
DOI:10.1021/op7001479
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: hydrogen; palladium 10% on activated carbon / 20 °C / 7500.75 Torr
2.1: n-butyllithium / tert-butyl methyl ether; hexane / 2.25 h / 0 - 20 °C / Inert atmosphere
2.2: 1.25 h / -30 - 20 °C / Inert atmosphere
With
n-butyllithium; palladium 10% on activated carbon; hydrogen;
In
hexane; tert-butyl methyl ether;
DOI:10.1021/op7001479
