3-AMINO-9-FLUORENONE

Base Information

• Chemical Name: 3-AMINO-9-FLUORENONE
• CAS No.: 6276-05-7
• Molecular Formula: C13H9NO
• Molecular Weight: 195.221
• Hs Code.: 2922399090
• European Community (EC) Number: 633-106-6
• NSC Number: 36449
• DSSTox Substance ID: DTXSID70284274
• Nikkaji Number: J81.175K
• Wikidata: Q82019158
• Mol file: 6276-05-7.mol

Synonyms:9-Fluorenone,3-amino- (6CI,8CI);3-Amino-9-fluorenone;3-Amino-9H-fluoren-9-one;NSC 36449;

Chemical Property of 3-AMINO-9-FLUORENONE

Chemical Property:

• Vapor Pressure: 2.38E-07mmHg at 25°C
• Melting Point: 154-155 °C(lit.)
• Refractive Index: 1.72
• Boiling Point: 422.6 °C at 760 mmHg
• PKA: 1.77±0.20(Predicted)
• Flash Point: 209.4 °C
• PSA: 43.09000
• Density: 1.327g/cm³
• LogP: 3.06140
• XLogP3: 2.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 195.068413911
• Heavy Atom Count: 15
• Complexity: 276

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C3=C(C2=O)C=CC(=C3)N

Technology Process of 3-AMINO-9-FLUORENONE

There total 4 articles about 3-AMINO-9-FLUORENONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

3-nitro-9H-fluoren-9-one (42135-22-8) → 3-amino-9-fluorenone (6276-05-7)

Guidance literature:

With ethanol; iron; Reflux;

Reference yield:

→ 3-amino-9-fluorenone (6276-05-7)

Guidance literature:

With sodium sulfide; ethanol; ammonium chloride;

DOI:10.1021/ja01184a058

Reference yield:

9-fluorenone (486-25-9,952573-42-1) → 3-amino-9-fluorenone (6276-05-7)

Guidance literature:

Multi-step reaction with 2 steps

1: sulfuric acid; nitric acid / water / 80 - 90 °C

2: iron; ethanol / Reflux

With ethanol; sulfuric acid; nitric acid; iron; In water;

upstream raw materials:

3-nitro-9H-fluoren-9-one

9-fluorenone

Downstream raw materials:

3-fluoro-9H-fluorene

N-(9-oxo-fluoren-3-yl)-acetamide

3-fluoro-9-fluorenone

2-bromofluoren-9-one

Refernces

• 1、 -. "Metallocene compounds, and preparation and use thereof for synthesis of poly-alpha-olefins as lubricating base oil". Paragraph 0058; 0060; 0080. . Retrieved 2018/10/04.
• 2、 -. "Electron donor of Ziegler-Natta catalyst and preparation method of electron donor". Paragraph 0048. . Retrieved 2016/10/10.