lithium (1-phenyl-3,3,5,5-tetrachlorocyclotriphosphazen-1-yl)triethylborate

Base Information

• Chemical Name: lithium (1-phenyl-3,3,5,5-tetrachlorocyclotriphosphazen-1-yl)triethylborate
• CAS No.: 86727-36-8
• Molecular Formula: C₁₂H₂₀BCl₄N₃P₃*Li
• Molecular Weight: 458.796
• Mol file: 86727-36-8.mol

Synonyms:

Chemical Property of lithium (1-phenyl-3,3,5,5-tetrachlorocyclotriphosphazen-1-yl)triethylborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of lithium (1-phenyl-3,3,5,5-tetrachlorocyclotriphosphazen-1-yl)triethylborate

There total 1 articles about lithium (1-phenyl-3,3,5,5-tetrachlorocyclotriphosphazen-1-yl)triethylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1'-diphenyl-3,3,3',3',5,5,5',5'-octachlorobi(cyclotriphosphazene) (21229-71-0) + lithium triethylborohydride (22560-16-3) → lithium (1-phenyl-3,3,5,5-tetrachlorocyclotriphosphazen-1-yl)triethylborate (86727-36-8)

Guidance literature:

In tetrahydrofuran; N2-atmosphere; 2.5 equivs. of LiBHEt3, stirring (2 h); (31)P-NMR spectroscopy;

DOI:10.1021/om00142a012

Reference yield: 10.0%

iodo(cyclopentadienyl)dicarbonylruthenium(II) + lithium (1-phenyl-3,3,5,5-tetrachlorocyclotriphosphazen-1-yl)triethylborate (86727-36-8) → (C6H5P3N3Cl4)Ru(C5H5)(CO)2 (104323-05-9)

Guidance literature:

In tetrahydrofuran; N2-atmosphere; 66°C (24 h); solvent removal (vac.), chromy. (SiO2, CH2Cl2/hexanes); elem. anal.;

DOI:10.1021/om00142a012

Reference yield: 8.0%

(η(5)-cyclopentadienyl)W(CO)3I + lithium (1-phenyl-3,3,5,5-tetrachlorocyclotriphosphazen-1-yl)triethylborate (86727-36-8) → (C6H5P3N3Cl4)W(C5H5)(CO)3 (104323-04-8)

Guidance literature:

In tetrahydrofuran; N2-atmosphere; 66°C (24 h); solvent removal (vac.), chromy. (SiO2, CH2Cl2/hexanes); elem. anal.;

DOI:10.1021/om00142a012

upstream raw materials:

1,1'-diphenyl-3,3,3',3',5,5,5',5'-octachlorobi(cyclotriphosphazene)

lithium triethylborohydride

Downstream raw materials:

Li⁽¹⁺⁾*(C₆H₅P₃N₃Cl₄)Cr(C₅H₅)(CO)3I^(1-)=Li[(C₆H₅P₃N₃Cl₄)Cr(C₅H₅)(CO)3I]

(C₆H₅P₃N₃Cl₄)Cr(C₅H₅)(CO)3

(C₆H₅P₃N₃Cl₄)Ru(C₅H₅)(CO)2

(C₆H₅P₃N₃Cl₄)W(C₅H₅)(CO)3

Refernces