DCzTRZ

Base Information

• Chemical Name: DCzTRZ
• CAS No.: 1106730-48-6
• Molecular Formula: C₄₅H₂₉N₅
• Molecular Weight: 639.759
• Mol file: 1106730-48-6.mol

Synonyms:

Chemical Property of DCzTRZ

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of DCzTRZ

There total 2 articles about DCzTRZ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(9,9’-(5-(4,4,5,5-tetramethyl-1,2,3-dioxaborolan-2-yl)-1,3-phenylene)bis(9H-carbazole)) (1082549-89-0) + 2-chloro-4,6-diphenyl-1,3,5-triazine (3842-55-5) → 9,9′-(5-(4,6-diphenyl-1,3,5-triazin-2-yl)-1,3-phenylene)bis(9Hcarbazole) (1106730-48-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In tetrahydrofuran;

DOI:10.1002/adma.201500267

Reference yield: 55.6%

2-chloro-4,6-diphenyl-1,3,5-triazine (3842-55-5) + 9-[3-(9H-carbazol-9-yl)-5-chloro]phenyl-9H-carbazole (1205555-26-5) → 9,9′-(5-(4,6-diphenyl-1,3,5-triazin-2-yl)-1,3-phenylene)bis(9Hcarbazole) (1106730-48-6)

Guidance literature:

9-[3-(9H-carbazol-9-yl)-5-chloro]phenyl-9H-carbazole; With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; potassium acetate; bis(pinacol)diborane; In 1,4-dioxane; at 110 ℃; for 2h; Inert atmosphere;

2-chloro-4,6-diphenyl-1,3,5-triazine; In 1,4-dioxane; water; at 110 ℃; for 18h;

upstream raw materials:

(9,9’-(5-(4,4,5,5-tetramethyl-1,2,3-dioxaborolan-2-yl)-1,3-phenylene)bis(9H-carbazole))

2-chloro-4,6-diphenyl-1,3,5-triazine

9-[3-(9H-carbazol-9-yl)-5-chloro]phenyl-9H-carbazole

Refernces

• 1、 -. "COMPOSITION OF MATTER FOR USE IN ORGANIC LIGHT-EMITTING DIODES". Paragraph 0474. . Retrieved 2019/08/22.