Boranediamine, N,N,N',N'-tetramethyl-1-phenyl-

Base Information

• Chemical Name: Boranediamine, N,N,N',N'-tetramethyl-1-phenyl-
• CAS No.: 1201-45-2
• Molecular Formula: C10H17BN2
• Molecular Weight: 176.069
• DSSTox Substance ID: DTXSID30415986
• Nikkaji Number: J2.870.062H
• Wikidata: Q82225089
• Mol file: 1201-45-2.mol

Synonyms:Boranediamine, N,N,N',N'-tetramethyl-1-phenyl-;1201-45-2;N-[dimethylamino(phenyl)boranyl]-N-methylmethanamine;Bis(dimethylamino)phenylboran;Bis(dimethylamino)phenylborane;SCHEMBL6441579;DTXSID30415986;InChI=1/C10H17BN2/c1-12(2)11(13(3)4)10-8-6-5-7-9-10/h5-9H,1-4H

Chemical Property of Boranediamine, N,N,N',N'-tetramethyl-1-phenyl-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 176.1484787
• Heavy Atom Count: 13
• Complexity: 134

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(C1=CC=CC=C1)(N(C)C)N(C)C

Technology Process of Boranediamine, N,N,N',N'-tetramethyl-1-phenyl-

There total 14 articles about Boranediamine, N,N,N',N'-tetramethyl-1-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

phenylborondichloride (873-51-8) + dimethyl amine (124-40-3) → Bis-(dimethylamino)-phenylboran (1201-45-2)

Guidance literature:

In pentane; at -78 - 20 ℃; Inert atmosphere;

DOI:10.1002/chem.201705913

Reference yield: 77.0%

chloro-bis(dimethylamino)borane (6562-41-0) + phenyllithium (591-51-5) → Bis-(dimethylamino)-phenylboran (1201-45-2)

Guidance literature:

In diethyl ether; -78°C;

Reference yield: 48.0%

tetrakis(dimethylamido)diborane (1630-79-1) + Phenyl triflate (17763-67-6) → Bis-(dimethylamino)-phenylboran (1201-45-2)

Guidance literature:

With 1,1'-bis-(diphenylphosphino)ferrocene; potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; In 1,4-dioxane; at 80 ℃; for 6h;

DOI:10.1016/S0040-4039(97)00642-4

upstream raw materials:

diethyl phenylboronate

tris(dimethylamino)aluminum

phenylborondichloride

dimethyl amine

Downstream raw materials:

3,6-diphenyl-cyclo-1,2,4,5-tetraaza-3,6-diborane

2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

2-phenyl-[1,3,2]diazaborinane

dimethyl amine

Refernces

• 1、 Ruff,J.K.. "-". . p. 1020 - 1023. Retrieved 1962.
• 2、 Ayhan, Ozan,Riensch, Nicolas A.,Glasmacher, Clemens,Helten, Holger. "Cyclolinear Oligo- and Poly(iminoborane)s: The Missing Link in Inorganic Main-Group Macromolecular Chemistry". supporting information. p. 5883 - 5894. Retrieved 2018/03/21.
• 3、 Cragg, R. Harry,Miller, Tim J.. "ORGANOBORON COMPOUNDS. XX. ALKYLAMINO- AND DIALKYLAMINO-PIPERIDINOPHENYLBORANES". . p. 143 - 150. Retrieved 2007/10/02.