Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)⁽¹⁺⁾*B(C₆H₅)4^(1-)*CH₃CN=[Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)]B(C₆H₅)4*CH₃CN

Base Information

• Chemical Name: Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)⁽¹⁺⁾*B(C₆H₅)4^(1-)*CH₃CN=[Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)]B(C₆H₅)4*CH₃CN
• CAS No.: 1379690-67-1
• Molecular Formula: C₂H₃N*C₂₂H₃₁MnN₄S*C₂₄H₂₀B
• Molecular Weight: 798.805
• Mol file: 1379690-67-1.mol

Synonyms:

Chemical Property of Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)⁽¹⁺⁾*B(C₆H₅)4^(1-)*CH₃CN=[Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)]B(C₆H₅)4*CH₃CN

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)⁽¹⁺⁾*B(C₆H₅)4^(1-)*CH₃CN=[Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)]B(C₆H₅)4*CH₃CN

There total 1 articles about Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)⁽¹⁺⁾*B(C₆H₅)4^(1-)*CH₃CN=[Mn(SC(CH₃)2C(CH₃)NC₃H₆N(CH₂C₅H₃(CH₃)N)2)]B(C₆H₅)4*CH₃CN which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

manganese (II) sulfate monohydrate + 3-mercapto-3-methyl-butan-2-one (42855-44-7) + N,N-bis(6-methyl-2-pyridylmethyl)propane-1,3-diamine (1379690-89-7) + sodium tetraphenyl borate (143-66-8) + acetonitrile (75-05-8,26809-02-9) → Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)(1+)*B(C6H5)4(1-)*CH3CN=[Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)]B(C6H5)4*CH3CN (1379690-67-1)

Guidance literature:

With NaOCH₃; In methanol; (N2); Schlenk technique; NaOMe/MeOH, butanone/MeOH were combined at -30°C; stirred (room temp., 30 min); added to Mn salt; soln. of diamine/MeOH was added dropwise; stirred (room temp., overnight); NaBPh4/MeOHwas added; stirred (2 d, room temp.); evapd. (vac.); stirred woth Et2O at room temp. for 30 min; filtered; dissolved in MeCN; stirred at room temp. for 1 h; filtered; concd.; layeredwith Et2O; cooled to -30°C overnight; filtered; elem. anal.;

DOI:10.1021/ic300192q

Reference yield:

Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)(1+)*B(C6H5)4(1-)*CH3CN=[Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2)]B(C6H5)4*CH3CN (1379690-67-1) → (Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2))2O(2+)*2B(C6H5)4(1-)=(Mn(SC(CH3)2C(CH3)NC3H6N(CH2C5H3(CH3)N)2))2O(B(C6H5)4)2

Guidance literature:

With air; In further solvent(s); (N2); Schlenk technique; soln. of Mn complex in EtCN was cooled to -80°C; exposed to air overnight; layered with cold (-80°C) Et2O; kept at -80°C for few wk;

DOI:10.1021/ic300192q

upstream raw materials:

3-mercapto-3-methyl-butan-2-one

N,N-bis(6-methyl-2-pyridylmethyl)propane-1,3-diamine

sodium tetraphenyl borate

acetonitrile

Refernces