Triphenyl[(4-chlorophenyl)imino]phosphorane

Base Information

• Chemical Name: Triphenyl[(4-chlorophenyl)imino]phosphorane
• CAS No.: 31641-65-3
• Molecular Formula: C24H19 Cl N P
• Molecular Weight: 387.848
• NSC Number: 126619
• DSSTox Substance ID: DTXSID40953607
• Nikkaji Number: J706.521C
• Wikidata: Q82932496
• Mol file: 31641-65-3.mol

Synonyms:31641-65-3;Triphenyl[(4-chlorophenyl)imino]phosphorane;(4-chlorophenyl)imino-triphenyl-lambda5-phosphane;N1-(1,1,1-TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)-4-CHLOROANILINE;4-Chloro-N-(triphenylphosphoranylidene)aniline;NSC126619;DTXSID40953607;AKOS024319252;NSC-126619;[(4-Chlorophenyl)imino](triphenyl)-lambda~5~-phosphane;N-(4-CHLOROPHENYL)-P,P,P-TRIPHENYLPHOSPHINE IMIDE

Chemical Property of Triphenyl[(4-chlorophenyl)imino]phosphorane

Chemical Property:

• Vapor Pressure: 6.6E-11mmHg at 25°C
• Boiling Point: 533.1°Cat760mmHg
• Flash Point: 276.2°C
• PSA: 22.17000
• Density: 1.14g/cm³
• LogP: 6.14920
• XLogP3: 7.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 387.0943643
• Heavy Atom Count: 27
• Complexity: 440

Purity/Quality:

99% ^*data from raw suppliers

N-(4-CHLOROPHENYL)-P,P,P-TRIPHENYLPHOSPHINE IMIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)P(=NC2=CC=C(C=C2)Cl)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Triphenyl[(4-chlorophenyl)imino]phosphorane

There total 9 articles about Triphenyl[(4-chlorophenyl)imino]phosphorane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

N-phenyltriphenyliminophosphorane (2325-27-1) → N-(o-chlorophenyl)triphenylphosphine imide (53120-47-1) + N-p-chlorophenyltriphenylphosphinimine (31641-65-3) + anilinotriphenylphosphonium chloride

Guidance literature:

With (Dichloroiodo)benzene; In benzene; at 20 ℃; Yield given. Title compound not separated from byproducts;

Reference yield: 71.0%

1-azido-4-chlorobenzene (3296-05-7) + triphenylphosphine (603-35-0) → N-p-chlorophenyltriphenylphosphinimine (31641-65-3)

Guidance literature:

In diethyl ether; for 2h; Heating;

DOI:10.1002/hlca.200590131

Reference yield:

1-azido-4-chlorobenzene (3296-05-7) + triphenylphosphine (603-35-0) → N-p-chlorophenyltriphenylphosphinimine (31641-65-3) + 4-chloro-aniline (106-47-8)

Guidance literature:

In tetrahydrofuran; water; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c8cc00179k

upstream raw materials:

4-chloro-aniline

dichlorotriphenylphosphorane

1-azido-4-chlorobenzene

triphenylphosphine

Downstream raw materials:

(4-chloro-phenyl)-(3,4-diphenyl-4H-[1,2,4]oxadiazol-5-ylidene)-amine

1-<1-(4-Chlorphenylimino)-3-hydroxy-2,3-bis(4-methoxyphenyl)-2-propenyl>-2-(pyrrolidino)-1-cyclopenten

1-<1-(4-Chlorphenylimino)-3-hydroxy-2,3-bis(4-methylphenyl)-2-propenyl>-2-pyrrolidino-1-cyclopenten

bis-(4-chloro-phenyl)-carbodiimide

Refernces

• 1、 He, Hua-Feng,Wang, Zhi-Jing,Bao, Weiliang. "Copper(II) acetate/oxygen-mediated nucleophilic addition and intramolecular C-H activation/C-N or C-C bond formation: One-pot synthesis of benzimidazoles or quinazolines". supporting information; experimental part. p. 2905 - 2912. Retrieved 2010/12/29.
• 2、 Katritzky, Alan R.,Khashab, Niveen M.,Bobrov, Sergey. "The preparation of 1,2,3-trisubstituted guanidines". . p. 1664 - 1675. Retrieved 2007/10/03.