(C₆H₅)2NBC₈H₁₄

Base Information

• Chemical Name: (C₆H₅)2NBC₈H₁₄
• CAS No.: 153255-45-9
• Molecular Formula: C₂₀H₂₄BN
• Molecular Weight: 289.228
• Mol file: 153255-45-9.mol

Synonyms:

Chemical Property of (C₆H₅)2NBC₈H₁₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₆H₅)2NBC₈H₁₄

There total 5 articles about (C₆H₅)2NBC₈H₁₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

9-borabicyclo[3.3.1]nonane dimer (21205-91-4) + ((((CH3)2CH)2C6H3NC(CH3))2CH)Ca(OC4H8)(N(C6H5)2) (947153-43-7) → (C6H5)2NBC8H14 (153255-45-9) + ((((CH3)2CH)2C6H3NC(CH3))2CH)Ca(OC4H8)(H2BC8H14)*((((CH3)2CH)2C6H3NC(CH3))2CH)Ca(OC4H8)(H2BC8H14)

Guidance literature:

In toluene; soln. of Ca compd. and B compd. in toluene stirred at room temp. for 1 h; extd. into hexane; filtered; crystd. by slow removal of solvent (Ca-B compd.); solvent removed from filtrate, Ph2NBC8H14 sublimed (130°C,4E-1 mbar);

DOI:10.1021/om070083t

Reference yield:

diphenylamine (122-39-4) + 9-bora-bicyclo[3.3.1]nonane (280-64-8) → (C6H5)2NBC8H14 (153255-45-9)

Guidance literature:

With [HC{(Me)CN(2,6-ⁱPr₂C₆H₃)}₂MgⁿBu]; In benzene-d6; at 60 ℃; for 144h; Inert atmosphere;

DOI:10.1002/anie.201505949

Reference yield:

9-borabicyclo[3.3.1]nonane dimer (21205-91-4) + diphenylamine (122-39-4) → (C6H5)2NBC8H14 (153255-45-9)

Guidance literature:

With Cp*Ti{MeC(NⁱPr)₂}(NBC₈H₁₄); at 60 ℃;

DOI:10.1021/jacs.5b06627

upstream raw materials:

9-borabicyclo[3.3.1]nonane dimer

((((CH₃)2CH)2C₆H₃NC(CH₃))2CH)Ca(OC₄H₈)(N(C₆H₅)2)

lithium diphenylamide

9-methoxy-9-BBN

Refernces

• 1、 Stevenson, Laura C.,Mellino, Simona,Clot, Eric,Mountford, Philip. "Reactions of titanium hydrazides with silanes and boranes: N-N bond cleavage and N atom functionalization". . p. 10140 - 10143. Retrieved 2015.