Technology Process of (5Z)-7-<3-endo-(carbobenzoxyamino)bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester
There total 13 articles about (5Z)-7-<3-endo-(carbobenzoxyamino)bicyclo<2.2.1>hept-2-exo-yl>heptenoic acid methyl ester which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 2 steps
1: dimsylsodium / dimethylsulfoxide / 4 h / 25 °C
2: 2.8 g / diethyl ether
With
dimsylsodium;
In
diethyl ether; dimethyl sulfoxide;
DOI:10.1021/jm00117a028
- Guidance literature:
-
Multi-step reaction with 7 steps
1: hydroxylamine hydrochloride, KOH / methanol / 0.5 h / 0 °C
2: 78.4 percent / LiAlH4 / tetrahydrofuran / 4 h / Heating
3: 1.97 g / pyridine / CH2Cl2 / 0.5 h / 0 °C
4: 100 percent / m-chloroperbenzoic acid / CH2Cl2 / 3 h / 20 °C
5: HIO4 / dioxane; H2O / 4 h / 25 °C
6: dimsylsodium / dimethylsulfoxide / 4 h / 25 °C
7: 2.8 g / diethyl ether
With
pyridine; potassium hydroxide; lithium aluminium tetrahydride; dimsylsodium; hydroxylamine hydrochloride; periodic acid; 3-chloro-benzenecarboperoxoic acid;
In
tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; dichloromethane; water; dimethyl sulfoxide;
DOI:10.1021/jm00117a028
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.97 g / pyridine / CH2Cl2 / 0.5 h / 0 °C
2: 100 percent / m-chloroperbenzoic acid / CH2Cl2 / 3 h / 20 °C
3: HIO4 / dioxane; H2O / 4 h / 25 °C
4: dimsylsodium / dimethylsulfoxide / 4 h / 25 °C
5: 2.8 g / diethyl ether
With
pyridine; dimsylsodium; periodic acid; 3-chloro-benzenecarboperoxoic acid;
In
1,4-dioxane; diethyl ether; dichloromethane; water; dimethyl sulfoxide;
DOI:10.1021/jm00117a028