trimethylaluminium lithium thiophenoxide

Base Information

• Chemical Name: trimethylaluminium lithium thiophenoxide
• CAS No.: 78426-82-1
• Molecular Formula: C₉H₁₄AlS*Li
• Molecular Weight: 188.199
• Mol file: 78426-82-1.mol

Synonyms:

Chemical Property of trimethylaluminium lithium thiophenoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trimethylaluminium lithium thiophenoxide

There total 1 articles about trimethylaluminium lithium thiophenoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethylaluminum (75-24-1) + thiophenol (108-98-5) → trimethylaluminium lithium thiophenoxide (78426-82-1)

Guidance literature:

With n-butyllithium; In hexane; soln. of Al(CH3)3 in hexane added to soln. of lithium benzenethiolate (prepared from org. compd. and n-butyllithium at 0°C) in THF at 0°C, reaction time 1 h; product not isolated;

DOI:10.1246/bcsj.54.274

Reference yield:

trimethylaluminium lithium thiophenoxide (78426-82-1) → 4-Benzenesulfinyl-2-benzo[1,3]dioxol-5-yl-4-methyl-5-oxo-tetrahydro-furan-3-carboxylic acid ethyl ester

Guidance literature:

Multi-step reaction with 2 steps

1: 3.) p-toluenesulfonic acid

2: m-CPBA, NaHPO₄

With camphor-10-sulfonic acid; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid;

DOI:10.1080/00397919208019284

Reference yield:

trimethylaluminium lithium thiophenoxide (78426-82-1) → 3-furancarboxylic acid, 2-(1,3-benzodioxol-5-yl)tetrahydro-4-methyl-5-oxo-4-(phenylthio)-, ethyl ester (141357-36-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 3.) p-toluenesulfonic acid

2: 1.) LDA

With toluene-4-sulfonic acid; lithium diisopropyl amide;

DOI:10.1080/00397919208019284

upstream raw materials:

trimethylaluminum

thiophenol

Downstream raw materials:

3-furancarboxylic acid, tetrahydro-2-(5-methyl-2-thienyl)-5-oxo-4-(phenylthio)-, ethyl ester

3-furancarboxylic acid, tetrahydro-5-oxo-4-(phenylthio)-2-<3-(trifluoromethyl)-phenyl>-, ethyl ester

3-furancarboxylic acid, 2-(1,3-benzodioxo-5-yl)tetrahydro-5-oxo-4-(phenylthio)-, ethyl ester

3-furancarboxylic acid, tetrahydro-2(1-naphthalenyl)-5-oxo-4-(phenylthio)-, ethyl ester

Refernces