3-methyl-1-p-tolyl-2,5-dihydro-1H-phosphole

Base Information

• Chemical Name: 3-methyl-1-p-tolyl-2,5-dihydro-1H-phosphole
• CAS No.: 96080-01-2
• Molecular Formula: C₁₂H₁₅P
• Molecular Weight: 190.225
• Mol file: 96080-01-2.mol

Synonyms:

Chemical Property of 3-methyl-1-p-tolyl-2,5-dihydro-1H-phosphole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 3-methyl-1-p-tolyl-2,5-dihydro-1H-phosphole

There total 2 articles about 3-methyl-1-p-tolyl-2,5-dihydro-1H-phosphole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(4-methylphenyl)-3-methyl-2,5-dihydro-1H-phosphole 1-oxide (13829-65-7) → 3-methyl-1-p-tolyl-2,5-dihydro-1H-phosphole (96080-01-2)

Guidance literature:

With trichlorosilane; In dichloromethane; at 0 ℃; for 3h;

DOI:10.1080/10426507.2018.1553043

Reference yield:

p-tolyldichlorophosphine (1005-32-9) + isoprene (78-79-5,9003-31-0) → 3-methyl-1-p-tolyl-2,5-dihydro-1H-phosphole (96080-01-2)

Guidance literature:

Multistep reaction; (i) cupric stearate, (ii) Mg, THF;

DOI:10.1021/jo01027a016

upstream raw materials:

p-tolyldichlorophosphine

isoprene

1-(4-methylphenyl)-3-methyl-2,5-dihydro-1H-phosphole 1-oxide

Refernces