phenyl pentafluorobenzenesulfonate

Base Information

• Chemical Name: phenyl pentafluorobenzenesulfonate
• CAS No.: 793-75-9
• Molecular Formula: C12H5 F5 O3 S
• Molecular Weight: 324.228
• Mol file: 793-75-9.mol

Synonyms:Benzenesulfonic acid, pentafluoro-,phenyl ester (7CI,8CI,9CI); NSC 146150; [[(Pentafluorophenyl)sulfonyl]oxy]benzene

Chemical Property of phenyl pentafluorobenzenesulfonate

Chemical Property:

• Vapor Pressure: 4.15E-05mmHg at 25°C
• Boiling Point: 362°Cat760mmHg
• Flash Point: 172.7°C
• Density: 1.588g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of phenyl pentafluorobenzenesulfonate

There total 3 articles about phenyl pentafluorobenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

pentafluorobenzenesulonyl chloride (832-53-1) + phenol (108-95-2,27073-41-2) → phenyl 2,3,4,5,6-pentafluorobenzenesulfonate (793-75-9)

Guidance literature:

In sodium hydroxide; at 60 - 70 ℃;

Reference yield:

pentafluorobenzensulfonyl fluoride (36650-04-1) + phenol (108-95-2,27073-41-2) → phenyl 2,3,4,5,6-pentafluorobenzenesulfonate (793-75-9)

Guidance literature:

With caesium carbonate; at 20 ℃; for 2h;

DOI:10.1021/jacs.9b06126

Reference yield:

→ phenyl 2,3,4,5,6-pentafluorobenzenesulfonate (793-75-9)

Guidance literature:

Pentafluorbenzolsulfonylchlorid + Phenol + wss. NaOH ;

upstream raw materials:

pentafluorobenzenesulonyl chloride

phenol

pentafluorobenzensulfonyl fluoride

Downstream raw materials:

benzonitrile

Refernces

• 1、 Laudadio, Gabriele,Bartolomeu, Aloisio De A.,Verwijlen, Lucas M. H. M.,Cao, Yiran,De Oliveira, Kleber T.,No?l, Timothy. "Sulfonyl Fluoride Synthesis through Electrochemical Oxidative Coupling of Thiols and Potassium Fluoride". supporting information. p. 11832 - 11836. Retrieved 2019/08/26.
• 2、 -. "Pentafluorobenzenesulfonamides and analogs". . . Retrieved 2008/06/13.