Ru(SC₆F₅)3(dimethylphenylphosphine)2

Base Information

• Chemical Name: Ru(SC₆F₅)3(dimethylphenylphosphine)2
• CAS No.: 112515-18-1
• Molecular Formula: C₃₄H₂₂F₁₅P₂RuS₃
• Molecular Weight: 974.74
• Mol file: 112515-18-1.mol

Synonyms:

Chemical Property of Ru(SC₆F₅)3(dimethylphenylphosphine)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(SC₆F₅)3(dimethylphenylphosphine)2

There total 2 articles about Ru(SC₆F₅)3(dimethylphenylphosphine)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

mer-{RuCl3(PMe2Ph)3} (14710-17-9,20500-70-3) + lead pentafluorothiophenolate (21459-27-8) → bis(dimethylphenylphosphine)tris(pentafluorothiophenolato)ruthenium(III) (112515-18-1,667421-45-6)

Guidance literature:

In acetone; byproducts: PbCl2; dry N2, room temp., 2 h; PbCl2 filtered off, crystn. on partial evapn. (reduced pressure) and ethanol addn.; elem. anal.;

DOI:10.1016/0022-328X(89)85432-4

Reference yield:

{RuCl3(dimethylphenylphosphine)3} (20500-70-3,14710-17-9) + lead pentafluorothiophenolate (21459-27-8) → bis(dimethylphenylphosphine)tris(pentafluorothiophenolato)ruthenium(III) (112515-18-1,667421-45-6)

Guidance literature:

In acetone; byproducts: PbCl2; treatment of RuCl3(PMe2Ph)3 with Pb(SC6F5)2 in acetone with reflux;

DOI:10.1039/c39870000261

Reference yield: 25.0%

carbon disulfide (75-15-0,12122-00-8) + Ru(SC6F5)3(dimethylphenylphosphine)2 (112515-18-1,667421-45-6) → Ru(S2CSC6F5)2(dimethylphenylphosphine)2 + trans-Ru(S2CSC6F5)(SC6F5)2(dimethylphenylphosphine)2

Guidance literature:

In acetone; N2 or Ar; addn. of excess CS2 to acetone soln. of Ru complex, stirring at room temp. for 30 min; solvent evapn. under reduced pressure, chromy. (aluminum oxide, 4:1 hexanes-dichloromethane), solvent removal under vac.; elem. anal.;

DOI:10.1021/ic034125r

upstream raw materials:

mer-{RuCl₃(PMe₂Ph)3}

lead pentafluorothiophenolate

{RuCl₃(dimethylphenylphosphine)3}

Refernces

• 1、 Catala, Rosa Maria,Cruz-Garritz, Diana,Hills, Adrian,Hughes, David L.,Richards, Raymonds L.,et al.. "A C-F-Ru Interaction in a complex: Preparation and X-Ray Structure of ". . p. 261 - 262. Retrieved 2007/10/02.