bis(tert-butyl isocyanide-κC)[4-fluoro-N-((2-[N-(4-fluorophenyl)carboximidoyl]cyclopenta-2,4-dien-1-ylidene)methyl)anilinido-κ**(2)N,N']copper(I)

Base Information

• Chemical Name: bis(tert-butyl isocyanide-κC)[4-fluoro-N-((2-[N-(4-fluorophenyl)carboximidoyl]cyclopenta-2,4-dien-1-ylidene)methyl)anilinido-κ**(2)N,N']copper(I)
• CAS No.: 1338078-90-2
• Molecular Formula: C₂₉H₃₁CuF₂N₄
• Molecular Weight: 537.135
• Mol file: 1338078-90-2.mol

Synonyms:

Chemical Property of bis(tert-butyl isocyanide-κC)[4-fluoro-N-((2-[N-(4-fluorophenyl)carboximidoyl]cyclopenta-2,4-dien-1-ylidene)methyl)anilinido-κ**(2)N,N']copper(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(tert-butyl isocyanide-κC)[4-fluoro-N-((2-[N-(4-fluorophenyl)carboximidoyl]cyclopenta-2,4-dien-1-ylidene)methyl)anilinido-κ**(2)N,N']copper(I)

There total 1 articles about bis(tert-butyl isocyanide-κC)[4-fluoro-N-((2-[N-(4-fluorophenyl)carboximidoyl]cyclopenta-2,4-dien-1-ylidene)methyl)anilinido-κ**(2)N,N']copper(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

(tert-butylisonitrile)(η5-cyclopentadienyl)copper(I) + 4-fluorophenyl isocyanide (24075-34-1) → bis(tert-butyl isocyanide-κC)[4-fluoro-N-((2-[N-(4-fluorophenyl)carboximidoyl]cyclopenta-2,4-dien-1-ylidene)methyl)anilinido-κ**(2)N,N']copper(I) (1338078-90-2)

Guidance literature:

In tetrahydrofuran; to THF soln. of CpCuCNtBu, p-FPhNC added; react. mixt. stirred for 16 h; volatiles removed under reduced pressure; solid extd. with warm hexane, filtered; concd., stored at 245 K; elem. anal.;

DOI:10.1107/S010827011101972X

upstream raw materials:

4-fluorophenyl isocyanide

Refernces