a-Chloroethyl acetate

Base Information

• Chemical Name: a-Chloroethyl acetate
• CAS No.: 5912-58-3
• Molecular Formula: C4H7 Cl O2
• Molecular Weight: 122.551
• Hs Code.: 9999999999
• Mol file: 5912-58-3.mol

Synonyms:Ethanol,1-chloro-, acetate (6CI,7CI,8CI,9CI);1-Acetoxy-1-chloroethane;1-Acetoxyethylchloride;1-Chloroethyl acetate;1-Chloroethyl methylthioformate;a-Chloroethyl acetate;

Chemical Property of a-Chloroethyl acetate

Chemical Property:

• Vapor Pressure: 0.85mmHg at 25°C
• Refractive Index: 1.449
• Boiling Point: 120-124 oC**
• Flash Point: 18.9±15.3 oC, Calc.*
• PSA: 26.30000
• Density: 1.116±0.06 g/cm3 (20 oC 760 Torr), Calc.*
• LogP: 1.13430
• Storage Temp.: Hygroscopic, Refrigerator, under inert atmosphere
• Solubility.: Chloroform (Sparingly), Methanol (Slightly)

Purity/Quality:

98%Min ^*data from raw suppliers

1-chloroethylacetate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of a-Chloroethyl acetate

There total 6 articles about a-Chloroethyl acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetyl chloride (75-36-5) + decalin (91-17-8) → 1-chloroethyl acetate (5912-58-3) + trans-Decalin (493-02-7) + (±)-1-((1R*,4aS*,8aS*)-1-hydroxydecahydronaphthalen-4ayl)ethanone + 1-((1RS,4aRS,8aRS)-1-chlorodecahydronaphthalen-4a-yl)ethanone + (±)-(1R*,4aS*,8aS*)-9-methylenedecahydro-1,4a-(epoxymethano)naphthalene (4752-31-2)

Guidance literature:

With aluminum (III) chloride; at 0 - 10 ℃; for 5h; Mechanism; Inert atmosphere;

DOI:10.1021/ja5062246

Reference yield:

acetyl chloride (75-36-5) → 1-chloroethyl acetate (5912-58-3) + ethylidene diacetate (542-10-9)

Guidance literature:

at 100 ℃;

Reference yield:

ethyl acetate (141-78-6) → 1-chloroethyl acetate (5912-58-3) + 2-chloro-1-acetoxyethane (542-58-5)

Guidance literature:

With chlorine; In neat (no solvent); Product distribution; Ambient temperature; chlorine substitution on the alcoholic chain of aliphatic C₂-C₈ n-alkyl acetates, chloroacetates, dichloroacetates and trichloroacetates; formation of monochloro isomers;

upstream raw materials:

ethyl acetate

chlorine

acetaldehyde

acetyl chloride

Downstream raw materials:

acetyl chloride

acetaldehyde

acetic acid

hydrogenchloride

Refernces

• 1、 Skakovskii, E. D.,Lamotkin, S. A.,Tychinskaya, L. Yu.. "Lifetime of acyloxy radicals produced by decomposition of acetylpropionyl peroxide". . p. 319 - 324. Retrieved 2007/10/03.
• 2、 Kophornen, Ilpo O. O.. "Chlorination of Carboxylic Acid Derivatives. X. Chlorine Substitution on the Alcohol Chain of Aliphatic C2-C8 Alkyl Chloro-, Dichloro- and Trichloroacetates". . p. 721 - 724. Retrieved 2007/10/02.