MoO(SC₆H₂(CH(CH₃)2)3)4^(1-)*P(C₆H₅)4⁽¹⁺⁾={MoO(SC₆H₂(CH(CH₃)2)3)4}{P(C₆H₅)4}

Base Information

• Chemical Name: MoO(SC₆H₂(CH(CH₃)2)3)4^(1-)*P(C₆H₅)4⁽¹⁺⁾={MoO(SC₆H₂(CH(CH₃)2)3)4}{P(C₆H₅)4}
• CAS No.: 97352-54-0
• Molecular Formula: C₂₄H₂₀P*C₆₀H₉₂MoOS₄
• Molecular Weight: 1392.99
• Mol file: 97352-54-0.mol

Synonyms:

Chemical Property of MoO(SC₆H₂(CH(CH₃)2)3)4^(1-)*P(C₆H₅)4⁽¹⁺⁾={MoO(SC₆H₂(CH(CH₃)2)3)4}{P(C₆H₅)4}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of MoO(SC₆H₂(CH(CH₃)2)3)4^(1-)*P(C₆H₅)4⁽¹⁺⁾={MoO(SC₆H₂(CH(CH₃)2)3)4}{P(C₆H₅)4}

There total 1 articles about MoO(SC₆H₂(CH(CH₃)2)3)4^(1-)*P(C₆H₅)4⁽¹⁺⁾={MoO(SC₆H₂(CH(CH₃)2)3)4}{P(C₆H₅)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

2,4,6-Triisopropylthiophenol (22693-41-0) + molybdenum(IV) chloride (13320-71-3) → hexakis(2,4,6-triisopropylbenzenethiolato)dimolybdenum(III) (97352-51-7) + MoO(SC6H2(CH(CH3)2)3)4(1-)*P(C6H5)4(1+)={MoO(SC6H2(CH(CH3)2)3)4}{P(C6H5)4} (97352-54-0)

Guidance literature:

With Na; In 1,2-dimethoxyethane; Schlenk, N2; the thiophenol in DME is treated with Na pieces, stirred at 50°C for 1 h, cooled to room temp., filtered, soln. of MoCl4 in DME is added, mixt. is stirred (room temp., 16 h), filtered (Celite), solid is washed (MeOH), Ph4PBr is added; resulting solid is the oxo product, filtrate is evapd. to dryness, residue is triturated with pentane, solid is filtered off, washed with MeOH, recrystd. (CH2Cl-MeCN); elem. anal.;

upstream raw materials:

2,4,6-Triisopropylthiophenol

molybdenum(IV) chloride

Refernces