Au(PPh)3Br

Base Information

• Chemical Name: Au(PPh)3Br
• CAS No.: 79384-10-4
• Molecular Formula: Br*C₁₈H₁₅AuP
• Molecular Weight: 539.161
• Mol file: 79384-10-4.mol

Synonyms:

Chemical Property of Au(PPh)3Br

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Au(PPh)3Br

There total 36 articles about Au(PPh)3Br which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + Acetyl bromide (506-96-7) → bromo(triphenylphosphine)gold(I) (79384-10-4,14243-65-3) + acetyl chloride (75-36-5)

Guidance literature:

In benzene-d6; at 25 ℃; for 0.25h; Glovebox;

DOI:10.1246/cl.130335

Reference yield: 100.0%

(triphenylphosphine)gold(I) chloride (14243-64-2) + potassium bromide (7558-02-3,7758-02-3) → bromo(triphenylphosphine)gold(I) (79384-10-4,14243-65-3)

Guidance literature:

In dichloromethane; water;

DOI:10.1039/c9dt02312g

Reference yield: 95.0%

dichlorocyanomethyl(triphenylphosphine)gold (90142-79-3) → bromo(triphenylphosphine)gold(I) (79384-10-4,14243-65-3)

Guidance literature:

With KBr; In chloroform; water; Au-compound in acetone was stirred with KBr in water for 1 h; aq. layer sepd., org. layer washed (water), dried (K2CO3), solvent removed in vacuo, residue treated with benzene, filtered, petroleum ether added to the filtrate;

DOI:10.1007/BF00954488

upstream raw materials:

(triphenylphosphine)gold(I) chloride

(DBP)3AuBr

triphenylphosphinegold(III) tribromide

copper(I) bromide

Downstream raw materials:

triphenylphosphinegold(III) tribromide

(C₆H₅)3PAu(CC(O)OC(CH₃)2OC(CH₃))

(2,6-dimethoxyphenyl)(triphenylphosphine)gold(I)

trans-((triphenylphosphine)gold(III)BrCl₂)

Refernces

• 1、 Rousselle, Benjamin,Bouyer, Florence,Bayardon, Jér?me,Laly, Myriam,Ghiringhelli, Fran?ois,Rousselin, Yoann,Bodio, Ewen,Malacea-Kabbara, Raluca. "Development of a novel highly anti-proliferative family of gold complexes: Au(i)-phosphonium-phosphines". . p. 4880 - 4889. Retrieved 2021/04/22.
• 2、 Kang, Xi,Xiong, Lin,Wang, Shuxin,Yu, Haizhu,Jin, Shan,Song, Yongbo,Chen, Tao,Zheng, Liwei,Pan, Chensong,Pei, Yong,Zhu, Manzhou. "Shape-Controlled Synthesis of Trimetallic Nanoclusters: Structure Elucidation and Properties Investigation". . p. 17145 - 17150. Retrieved 2016/11/23.