Bis(pentafluorophenyl) perdisulfide

Base Information

• Chemical Name: Bis(pentafluorophenyl) perdisulfide
• CAS No.: 1494-06-0
• Molecular Formula: C12F10S2
• Molecular Weight: 398.248
• Hs Code.: 2930909090
• Mol file: 1494-06-0.mol

Synonyms:1,1',2,2'3,3',4,4',5,5'-decafluorodiphenyl disulfide;

Chemical Property of Bis(pentafluorophenyl) perdisulfide

Chemical Property:

• PSA: 50.60000
• LogP: 5.87700

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Bis(pentafluorophenyl) perdisulfide

There total 121 articles about Bis(pentafluorophenyl) perdisulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pentafluorophenylthiol (771-62-0) → bis(pentafluorophenyl) disulfide (1494-06-0)

Guidance literature:

With sodium perborate; acetic acid; at 20 ℃; for 2h;

DOI:10.1002/chem.200400754

Reference yield: 78.0%

lead pentafluorothiophenolate (21459-27-8) → tris(pentafluorophenylmercapto)phosphine (31572-57-3) + bis(pentafluorophenyl) disulfide (1494-06-0)

Guidance literature:

With phosphorus pentachloride; In pentane; at 0 ℃;

Reference yield: 69.0%

pentafluorophenylthiol (771-62-0) → pentafluorobenzenesulfenyl chloride (27918-31-6) + bis(pentafluorophenyl) disulfide (1494-06-0)

Guidance literature:

With phosphorus pentachloride; at 100 ℃; for 5h;

DOI:10.1134/S1070428016020068

upstream raw materials:

diethyl ether

2-(pentafluorophenylsulfanyl)-1-phenylethanone

Bis(trifluoromethyl)disulfid

pentafluorobenzenesulfenyl chloride

Downstream raw materials:

bis(pentafluorophenyl)thioselane

n-C₄H₉B(SC₆F₅)2

Bis<(pentafluorophenyl)thio>phenylboran

(4-nitrophenyl)(perfluorophenyl)sulfane

Refernces

• 1、 Tahara, Keishiro,Matsuzaki, Ayaka,Masuko, Takahiro,Kikuchi, Jun-Ichi,Hisaeda, Yoshio. "Synthesis, characterization, Co-S bond reactivity of a vitamin B 12 model complex having pentafluorophenylthiolate as an axial ligand". . p. 6410 - 6416. Retrieved 2013.
• 2、 Makarov, Alexander Yu.,Bagryanskaya, Irina Yu.,Zhivonitko, Vladimir V.. "Interaction of 1,3λ4δ2,2,4-benzodithiadiazines with neutral and charged S-electrophiles: SCl2, C6F5SCl, and NS2+". . p. 968 - 972. Retrieved 2020/08/26.
• 3、 Nikul'shin,Maksimov,Platonov. "Synthesis of chloropolyfluoroarenes from polyfluoroarenethiols and PCl5". . p. 200 - 205. Retrieved 2016/04/19.