Oxobismuthanylium;nitrate

Base Information

• Chemical Name: Oxobismuthanylium;nitrate
• CAS No.: 10361-46-3
• Molecular Formula: BiNO4
• Molecular Weight: 286.985
• Mol file: 10361-46-3.mol

Synonyms:

Chemical Property of Oxobismuthanylium;nitrate

Chemical Property:

• Appearance/Colour: White powder
• Vapor Pressure: 49.8mmHg at 25°C
• Melting Point: 260, decomposing [HAW93]
• Boiling Point: 83oC at 760 mmHg
• PSA: 419.34000
• Density: 4.93
• LogP: -0.98120
• Water Solubility.: Insoluble in water. Soluble in acids.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 286.96313
• Heavy Atom Count: 6
• Complexity: 20.8

Purity/Quality:

99% ^*data from raw suppliers

Bismuth nitrate oxide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O, Xi
• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 17-26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [N+](=O)([O-])[O-].O=[Bi+]
• Physical properties: White powder; density 4.93 g/cm3; decomposes at 260°C; insoluble in water and ethanol; dissolves in acids.
• Uses: Bismuth oxynitrate is used in cosmetics, enamel fluxes and ceramic glazes. Medical applications include treatment of diarrhea, and gastric ulcers; and opacifier in x-ray diagnosis of alimentary canal . Bismuth(III) nitrate oxide is used as an organic chemical synthesis intermediate. It is also used in the spectrophotometric detection of bismuth.

Technology Process of Oxobismuthanylium;nitrate

There total 11 articles about Oxobismuthanylium;nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bismuth(III) oxide (1304-76-3) → bismuth subnitrate (10361-46-3) + bismutum subnitricum

Guidance literature:

In nitric acid; aq. HNO3; formation of the sparingly soluble basic salts; solution of the salts if H(1+)-activity exceeds 0.06;;

DOI:10.1021/ja01146a001

Reference yield:

bismuth (7440-69-9) + nitric acid (7697-37-2,78989-43-2) → bismuth subnitrate (10361-46-3)

Guidance literature:

With water; In nitric acid; byproducts: N oxide; preparation of a layer of 165 g remolten Bi (description of method given) and solvation at 60-70°C in 1040 ml 25% HNO3; vigorous reaction, form. of N oxide; filtration and evaporation in porcelain crucibles; addition of 800 ml H2O under stirring;; addition of the mass to hot water and washing the precipitate with H2O; drying with alcohol and heating at 45°C;;

Reference yield:

bismuth (III) nitrate pentahydrate → bismuth subnitrate (10361-46-3)

Guidance literature:

In neat (no solvent); drying over H2SO4 or in a stream of CO2 or dry air to constant weight;;

upstream raw materials:

bismuth(III) oxide

bismuth(III) nitrate

nitric acid

bismuth

Downstream raw materials:

water

Nitrate

bismuth(III)

bismuth(III) oxide iodide

Refernces

• 1、 Swinehart, D. F.,Garrett, A. B.. "". . p. 507 - 510. Retrieved 1951.
• 2、 Meng, Lei,Zheng, Liaoying,Cheng, Lihong,Zheng, Yao,Li, Guorong,Bernik, Slavko. "Enhancement of the electrical stability of ZnO varistors by a novel immersion process". . p. 2939 - 2945. Retrieved 2011.