1-Methylheptyl(trimethylsilyl) ether

Base Information

• Chemical Name: 1-Methylheptyl(trimethylsilyl) ether
• CAS No.: 18023-52-4
• Molecular Formula: C11H26OSi
• Molecular Weight: 202.412
• Hs Code.: 2931900090
• Mol file: 18023-52-4.mol

Synonyms:2-octyl trimethylsilyl ether;2-trimethylsilanyloxy-octane;

Chemical Property of 1-Methylheptyl(trimethylsilyl) ether

Chemical Property:

• PSA: 9.23000
• LogP: 4.19680

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Methylheptyl(trimethylsilyl) ether

There total 16 articles about 1-Methylheptyl(trimethylsilyl) ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

rac-octan-2-ol (4128-31-8,113301-48-7,4128-32-9) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) → trimethyl-(1-methyl-heptyloxy)-silane (18023-52-4)

Guidance literature:

With copper(II) bis(trifluoromethanesulfonate); In acetonitrile; at 20 ℃; for 0.666667h;

DOI:10.1016/S0040-4039(02)02780-6

Reference yield: 98.0%

1,1,1,2,2,2-hexamethyldisilane (1450-14-2) + rac-octan-2-ol (4128-31-8,113301-48-7,4128-32-9) → trimethyl-(1-methyl-heptyloxy)-silane (18023-52-4)

Guidance literature:

With lanthanum(III) nitrate hexahydrate; In acetonitrile; at 20 ℃;

DOI:10.1080/10426500802509616

Reference yield: 96.0%

rac-octan-2-ol (4128-31-8,113301-48-7,4128-32-9) + N-trimethylsilylaniline (3768-55-6) → trimethyl-(1-methyl-heptyloxy)-silane (18023-52-4)

Guidance literature:

With tetrabutyl ammonium fluoride; In N,N-dimethyl-formamide; at 20 ℃; for 0.0833333h;

DOI:10.1055/s-2005-872098

upstream raw materials:

rac-octan-2-ol

Hexamethyldisiloxane

methyl 2-octyl ether

trimethylsilyl iodide

Downstream raw materials:

2-iodooctane

2-Octyl acetate

2-octyl cyanide

2-isocyanatooctane

Refernces

• 1、 Zeynizadeh, Behzad,Sorkhabi, Serve. "Fast and efficient method for Silylation of alcohols and phenols with HMDS in the presence of bis-thiourea complexes of cobalt, nickel, copper and zinc chlorides". . p. 127 - 135. Retrieved 2018/02/06.
• 2、 Khusainova,Khafizova,Tyumkina,Dzhemilev. "Synthesis of 1-fluoro-2-alkylboriranes by the reaction of α-olefins with BF3·THF catalyzed by Cp2TiCl2". . p. 1438 - 1441. Retrieved 2016/08/10.