(Allyloxy)triphenylsilane

Base Information

• Chemical Name: (Allyloxy)triphenylsilane
• CAS No.: 18752-15-3
• Molecular Formula: C21H20OSi
• Molecular Weight: 316.475
• European Community (EC) Number: 621-544-0
• Nikkaji Number: J1.162.888E
• Mol file: 18752-15-3.mol

Synonyms:(Allyloxy)triphenylsilane;18752-15-3;(allyloxy)(triphenyl)silane;SCHEMBL3241358;AKOS024338568

Chemical Property of (Allyloxy)triphenylsilane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 316.128341792
• Heavy Atom Count: 23
• Complexity: 303

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CCO[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of (Allyloxy)triphenylsilane

There total 5 articles about (Allyloxy)triphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

allyl alcohol (107-18-6) + HSiPh3 (789-25-3) → allyloxytriphenylsilane (18752-15-3)

Guidance literature:

With air; hydrido(triphenylphosphine)copper(I) hexamer; In benzene; for 4h; Ambient temperature;

Reference yield: 90.0%

N-cyclohexyl(triphenylsilyl)methaneamide (1256450-18-6) + allyl alcohol (107-18-6) → allyloxytriphenylsilane (18752-15-3)

Guidance literature:

In ⁽²⁾H₈-toluene; at 180 ℃; for 1.75h; Sealed tube;

DOI:10.1039/c0dt00323a

Reference yield:

Allyl acetate (591-87-7) + triphenylhydroxysilane (791-31-1) → allyloxytriphenylsilane (18752-15-3)

Guidance literature:

bis(1,5-cyclooctadiene)iridium(I) tetrafluoroborate; In toluene; at 100 ℃; for 15h;

upstream raw materials:

allyl alcohol

HSiPh₃

Allyl acetate

triphenylhydroxysilane

Refernces

• 1、 Harinath, Adimulam,Bhattacharjee, Jayeeta,Anga, Srinivas,Panda, Tarun K.. "Dehydrogenative Coupling of Hydrosilanes and Alcohols by Alkali Metal Catalysts for Facile Synthesis of Silyl Ethers". . p. 724 - 730. Retrieved 2017/05/31.
• 2、 -. "Process for the preparation of vinyl- or allyl-containing compounds". Page/Page column 6. . Retrieved 2008/06/13.