5-(ETHOXYMETHYL)-2-FURALDEHYDE

Base Information

• Chemical Name: 5-(ETHOXYMETHYL)-2-FURALDEHYDE
• CAS No.: 1917-65-3
• Molecular Formula: C8H10O3
• Molecular Weight: 154.166
• Hs Code.: 2932190090
• Mol file: 1917-65-3.mol

Synonyms:5-(Ethoxymethyl)furan-2-carbaldehyde;

Chemical Property of 5-(ETHOXYMETHYL)-2-FURALDEHYDE

Chemical Property:

• Refractive Index: n20/D1.511
• Boiling Point: 234.258 °C at 760 mmHg
• Flash Point: 95.476 °C
• PSA: 39.44000
• Density: 1.104 g/cm³
• LogP: 1.62860
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

5-(Ethoxymethyl)furan-2-carboxaldehyde 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 41
• Safety Statements: 26-39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 5-(ETHOXYMETHYL)-2-FURALDEHYDE

There total 111 articles about 5-(ETHOXYMETHYL)-2-FURALDEHYDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

5-hydroxymethyl-2-furfuraldehyde (67-47-0) + ethanol (64-17-5) → 5-(ethoxymethyl)furfural (1917-65-3) + 4-oxopentanoic acid ethyl ester (539-88-8)

Guidance literature:

With dual acidic Glu-TsOH-Ti catalyst; at 90 ℃; for 6h; Reagent/catalyst;

DOI:10.1016/j.catcom.2018.02.026

Reference yield: 79.0%

D-Fructose (57-48-7,18875-34-8) + ethanol (64-17-5) → 5-(ethoxymethyl)furfural (1917-65-3) + 4-oxopentanoic acid ethyl ester (539-88-8)

Guidance literature:

With poly(p-styrenesulfonic acid)-grafted carbon nanotubes; at 100 ℃; for 12h; chemoselective reaction; Sealed tube; Green chemistry;

DOI:10.1039/c3gc41139g

Reference yield: 74.0%

5-bromomethyl-furan-2-carbaldehyde (39131-44-7) + ethanol (64-17-5) → 5-(ethoxymethyl)furfural (1917-65-3) + 4-oxopentanoic acid ethyl ester (539-88-8)

Guidance literature:

With calcium carbonate; for 1h; Reflux;

DOI:10.1016/j.carres.2013.04.002

upstream raw materials:

5-bromomethyl-furan-2-carbaldehyde

ethanol

D-Fructose

Sucrose

Downstream raw materials:

(2-furyl)methyl alcohol

2-(ethoxymethyl)-5-methylfuran

(5-(ethoxymethyl)furan-2-yl)methanol

2-(methoxymethyl)furan

Refernces

• 1、 Raveendra,Rajasekhar,Srinivas,Sai Prasad,Lingaiah. "Selective etherification of hydroxymethylfurfural to biofuel additives over Cs containing silicotungstic acid catalysts". . p. 105 - 113. Retrieved 2016.
• 2、 Antunes, Margarida M.,Russo, Patrícia A.,Wiper, Paul V.,Veiga, Jacinto M.,Pillinger, Martyn,Mafra, Luís,Evtuguin, Dmitry V.,Pinna, Nicola,Valente, Anabela A.. "Sulfonated graphene oxide as effective catalyst for conversion of 5-(hydroxymethyl)-2-furfural into biofuels". . p. 804 - 812. Retrieved 2014.
• 3、 Kumari, P. Krishna,Rao, B. Srinivasa,Padmakar,Pasha, Nayeem,Lingaiah. "Lewis acidity induced heteropoly tungustate catalysts for the synthesis of 5-ethoxymethyl furfural from fructose and 5-hydroxymethylfurfural". . p. 108 - 115. Retrieved 2018.
• 4、 Neves, Patricia,Antunes, Margarida M.,Russo, Patricia A.,Abrantes, Joana P.,Lima, Sergio,Fernandes, Auguste,Pillinger, Martyn,Rocha, Silvia M.,Ribeiro, Maria F.,Valente, Anabela A.. "Production of biomass-derived furanic ethers and levulinate esters using heterogeneous acid catalysts". . p. 3367 - 3376. Retrieved 2013.
• 5、 Wang, Hongliang,Deng, Tiansheng,Wang, Yingxiong,Cui, Xiaojing,Qi, Yongqin,Mu, Xindong,Hou, Xianglin,Zhu, Yulei. "Graphene oxide as a facile acid catalyst for the one-pot conversion of carbohydrates into 5-ethoxymethylfurfural". . p. 2379 - 2383. Retrieved 2013.
• 6、 Collins, Maurice N.,Hafizi, Hamid,Iqbal, Javed,Leahy, J. J.,Walker, Gavin. "Catalytic etherification of 5-hydroxymethylfurfural into 5-ethoxymethyfurfural over sulfated bimetallic SO42?/Al-Zr/KIT-6, a Lewis/Br?nsted acid hybrid catalyst". . . Retrieved 2020.
• 7、 Russo, Patricia A.,Antunes, Margarida M.,Neves, Patricia,Wiper, Paul V.,Fazio, Enza,Neri, Fortunato,Barreca, Francesco,Mafra, Luis,Pillinger, Martyn,Pinna, Nicola,Valente, Anabela A.. "Mesoporous carbon-silica solid acid catalysts for producing useful bio-products within the sugar-platform of biorefineries". . p. 4292 - 4305. Retrieved 2014.
• 8、 Bai, Yuanyuan,Wei, Lu,Yang, Mengfei,Chen, Huiyong,Holdren, Scott,Zhu, Guanghui,Tran, Dat T.,Yao, Chunli,Sun, Runcang,Pan, Yanbo,Liu, Dongxia. "Three-step cascade over a single catalyst: Synthesis of 5-(ethoxymethyl)furfural from glucose over a hierarchical lamellar multi-functional zeolite catalyst". . p. 7693 - 7705. Retrieved 2018.
• 9、 Chen, Jinzhu,Zhao, Guoying,Chen, Limin. "Efficient production of 5-hydroxymethylfurfural and alkyl levulinate from biomass carbohydrate using ionic liquid-based polyoxometalate salts". . p. 4194 - 4202. Retrieved 2014.
• 10、 Gupta, Dinesh,Saha, Basudeb. "Dual acidic titania carbocatalyst for cascade reaction of sugar to etherified fuel additives". . p. 46 - 50. Retrieved 2018.