2-(Allyloxy)-1-naphthaldehyde

Base Information

• Chemical Name: 2-(Allyloxy)-1-naphthaldehyde
• CAS No.: 19530-43-9
• Molecular Formula: C14H12O2
• Molecular Weight: 212.248
• Hs Code.: 2912499000
• DSSTox Substance ID: DTXSID40377602
• Nikkaji Number: J657.122K
• Wikidata: Q82166873
• Mol file: 19530-43-9.mol

Synonyms:2-(Allyloxy)-1-naphthaldehyde;19530-43-9;2-(prop-2-en-1-yloxy)naphthalene-1-carbaldehyde;2-prop-2-enoxynaphthalene-1-carbaldehyde;2-allyloxy-naphthaldehyde;SCHEMBL4266742;DTXSID40377602;LWQBRUUHCKGAEN-UHFFFAOYSA-N;MFCD00231645;STK199250;2-Allyloxy-naphthalene-1-carbaldehyde;AKOS000295641;CS-0318346;FT-0680000;11F-907;2-[(Prop-2-en-1-yl)oxy]naphthalene-1-carbaldehyde;J-506187

Chemical Property of 2-(Allyloxy)-1-naphthaldehyde

Chemical Property:

• Melting Point: 81-83°C
• Boiling Point: 379.9±17.0 °C(Predicted)
• PSA: 26.30000
• Density: 1.133±0.06 g/cm3(Predicted)
• LogP: 3.21710
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 212.083729621
• Heavy Atom Count: 16
• Complexity: 249

Purity/Quality:

98%min ^*data from raw suppliers

2-(Allyloxy)-1-naphthaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCOC1=C(C2=CC=CC=C2C=C1)C=O

Technology Process of 2-(Allyloxy)-1-naphthaldehyde

There total 3 articles about 2-(Allyloxy)-1-naphthaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

allyl bromide (106-95-6) + 2-hydroxynaphthalene-1-carbaldehyde (708-06-5) → 2-allyloxy-1-naphthaldehyde (19530-43-9)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide;

DOI:10.1039/c3cc47397j

Reference yield:

3-chloroprop-1-ene (107-05-1) + 2-hydroxynaphthalene-1-carbaldehyde (708-06-5) → 2-allyloxy-1-naphthaldehyde (19530-43-9)

Guidance literature:

DOI:10.1016/j.tetlet.2008.05.062

Reference yield:

→ 2-allyloxy-1-naphthaldehyde (19530-43-9)

Guidance literature:

2-Hydroxy-1-formyl-naphthalin, Allylbromid, wfr. K2CO3, sd. Acn., 48 h;

DOI:10.1039/jr9630000491

upstream raw materials:

allyl bromide

2-hydroxynaphthalene-1-carbaldehyde

3-chloroprop-1-ene

Downstream raw materials:

1,2,3,3a,4,11c-hexahydronaphtho<1',2':5,6>pyrano<4,3-c>pyrazolium chloride

C₂₀H₁₈N₂O₄

Refernces

• 1、 Zhang, Liang,Liu, Jie,Gao, Junkuo,Lu, Rong,Liu, Fang. "Adjustment of the solid fluorescence of a chalcone derivative through controlling steric hindrance". . p. 46354 - 46357. Retrieved 2017.
• 2、 Kuang, Kaimo,Wu, Meixia,Wu, Sixin,Xia, Ziqin,Xu, Qiankun,Zhang, Man,Zhou, Nengneng. "tert-Butyl Hydroperoxide-Initiated Radical Cyclization of 1-(Allyloxy)-2-(1-Arylvinyl)Benzenes with Sulfinic Acids to Access Sulfonated Benzoxepines". supporting information. p. 3491 - 3495. Retrieved 2021/06/28.
• 3、 He, Xiang-Kui,Cai, Bao-Gui,Yang, Qing-Qing,Wang, Long,Xuan, Jun. "Visible-Light-Promoted Cascade Radical Cyclization: Synthesis of 1,4-Diketones Containing Chroman-4-One Skeletons". supporting information. p. 3269 - 3273. Retrieved 2019/09/17.