BENZENESULFONIC ACID PHENYL ESTER

Base Information

• Chemical Name: BENZENESULFONIC ACID PHENYL ESTER
• CAS No.: 4358-63-8
• Molecular Formula: C12H10O3S
• Molecular Weight: 234.276
• Hs Code.: 2906299090
• Mol file: 4358-63-8.mol

Synonyms:phenyl phenylsulfonate;phenyl benzenesulphonate;Benzenesulfonic acid,phenyl ester;Phenylsulfonic acid phenyl ester;phenoxysulfonylbenzene;phenyl p-toluenesulfonate;Benzolsulfonsaeure-phenylester;

Chemical Property of BENZENESULFONIC ACID PHENYL ESTER

Chemical Property:

• Vapor Pressure: 1.66E-05mmHg at 25°C
• Boiling Point: 375.6°C at 760 mmHg
• Flash Point: 181°C
• PSA: 51.75000
• Density: 1.279g/cm³
• LogP: 3.53510

Purity/Quality:

97% ^*data from raw suppliers

Phenylbenzenesulfonate 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of BENZENESULFONIC ACID PHENYL ESTER

There total 31 articles about BENZENESULFONIC ACID PHENYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

N-methoxy-N-(phenylsulfonyl)benzenesulfonamide + phenol (108-95-2,27073-41-2) → phenyl benzenesulfonate (4358-63-8)

Guidance literature:

With potassium carbonate; In acetonitrile; at 80 ℃;

Reference yield: 97.0%

benzenesulfonyl chloride (98-09-9) + phenol (108-95-2,27073-41-2) → phenyl benzenesulfonate (4358-63-8)

Guidance literature:

With triethylamine; In dichloromethane; at 0 - 20 ℃; for 6h; Inert atmosphere;

DOI:10.1080/00397911.2017.1393088

Reference yield: 97.0%

sodium benzenesulfonate (873-55-2) + phenol (108-95-2,27073-41-2) → phenyl benzenesulfonate (4358-63-8)

Guidance literature:

In water; acetonitrile; at 20 ℃; for 2h; Reagent/catalyst; Solvent; Electrochemical reaction;

DOI:10.1021/acs.joc.1c00260

upstream raw materials:

sodium phenoxide

benzenesulfonyl chloride

benzene

phenol

Downstream raw materials:

phenyl 5-methyl-2-thienyl sulfone

3-Benzenesulfonyl-1-methyl-pyrrolidin-2-one

5-chloro-8-phenoxyquinoline

N-benzoylcyclohexylamine

Refernces

• 1、 Perez, Kaitlyn A.,Rogers, Cameron R.,Weiss, Emily A.. "Quantum Dot-Catalyzed Photoreductive Removal of Sulfonyl-Based Protecting Groups". supporting information. p. 14091 - 14095. Retrieved 2020/06/08.
• 2、 Alam, Mohammad Shariful,Koo, Sangho. "Deprotection of durable benzenesulfonyl protection for phenols — efficient synthesis of polyphenols". supporting information. p. 247 - 254. Retrieved 2018/01/08.