Benzenethiol, cadmium salt

Base Information

• Chemical Name: Benzenethiol, cadmium salt
• CAS No.: 21094-83-7
• Molecular Formula: C6H6S.1/2Cd
• Molecular Weight: 330.753
• Mol file: 21094-83-7.mol

Synonyms:

Chemical Property of Benzenethiol, cadmium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenethiol, cadmium salt

There total 6 articles about Benzenethiol, cadmium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

phenylthiotrimethylsilane (4551-15-9) + dimethylcadmium (506-82-1) → Bis-(phenylmercapto)-cadmium (21094-83-7)

Guidance literature:

In dichloromethane; byproducts: Si(CH3)4; PhSSiMe3 added to CdMe2 in CH2Cl2, heptane added after 48 h; filtered, dried under vacuum;

Reference yield:

cadmium(II) nitrate tetrhydrate + (Me4N)2[Cd4(SPh)10] → Bis-(phenylmercapto)-cadmium (21094-83-7)

Guidance literature:

In not given; in acetone or MeCN; not isolated;

DOI:10.1021/ja00333a064

Reference yield:

thiophenol (108-98-5) + cadmium (7440-43-9) → Bis-(phenylmercapto)-cadmium (21094-83-7)

Guidance literature:

In acetonitrile; Electrolysis; elem. anal.;

upstream raw materials:

phenylthiotrimethylsilane

dimethylcadmium

thiophenol

cadmium

Downstream raw materials:

Cd(C₆H₅S)2(C₁₀H₈N₂)

Cd(C₆H₅S)(S₂CSC₆H₅)

2Cd(C₆H₅S)2*(CH₃)4CH₂CH₂N₂=(Cd(C₆H₅S)2)2*(CH₃)4CH₂CH₂N₂

Refernces

• 1、 Osakada, Kohtaro,Yamamoto, Takakazu. "Formation of ZnS and CdS by Thermolysis of Homoleptic Thiolato Compounds n (M=Zn, Cd)". . p. 1117 - 1118. Retrieved 1987.
• 2、 Dean, Philip A. W.,Vittal, Jagadese J.. "". . p. 6436 - 6437. Retrieved 1984.
• 3、 Black, S. Jill,Einstein,Hayes, Peter C.,Kumar, Rajesh,Tuck, Dennis G.. "Reactions of Cd(SR)2 (R = n-butyl, phenyl) and the molecular structure of the 2,2′-bipyridine adduct of bis(n-butyl thioxanthato)cadmium(II)". . p. 4181 - 4184. Retrieved 2008/10/08.