Disulfide, ethyl phenylmethyl

Base Information

• Chemical Name: Disulfide, ethyl phenylmethyl
• CAS No.: 21230-16-0
• Molecular Formula: C9H12S2
• Molecular Weight: 184.326
• Mol file: 21230-16-0.mol

Synonyms:

Chemical Property of Disulfide, ethyl phenylmethyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Disulfide, ethyl phenylmethyl

There total 9 articles about Disulfide, ethyl phenylmethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-(ethyldisulfaneyl)pyridine (60681-89-2) + phenylmethanethiol (100-53-8) → n-propyl phenyl disulfide (21230-16-0)

Guidance literature:

With dmap; In dichloromethane; for 0.5h; Ambient temperature;

DOI:10.1016/S0040-4039(00)93965-0

Reference yield: 78.0%

Diethyl disulfide (110-81-6) + dibenzyl disulphide (150-60-7) → n-propyl phenyl disulfide (21230-16-0)

Guidance literature:

With N-fluorobis(benzenesulfon)imide; In 1,2-dichloro-ethane; at 50 ℃; for 4h; Schlenk technique; Sealed tube;

DOI:10.1016/j.cclet.2021.12.073

Reference yield: 62.0%

sodium ethanesulfinate (20035-08-9) + benzyl chloride (100-44-7) → n-propyl phenyl disulfide (21230-16-0)

Guidance literature:

benzyl chloride; With Sodium thiosulfate pentahydrate; In ethanol; water; at 100 ℃; for 2h; Inert atmosphere;

sodium ethanesulfinate; In 1,4-dioxane; at 110 ℃; for 11h; Inert atmosphere;

upstream raw materials:

phenylmethanethiol

ethanethiol

Diethyl disulfide

dibenzyl disulphide

Refernces

• 1、 Jayasuriya,Regen. "A convenient procedure for converting organic thiols into ethyldithio derivatives". . p. 451 - 452. Retrieved 1992.
• 2、 -. "Aryl-aryl, aryl-alkyl, alkyl-alkyl asymmetric the sulfur compounds and its synthetic method". Paragraph 0176-0179. . Retrieved 2016/11/17.
• 3、 Caraballo, Remi,Rahm, Martin,Vongvilai, Pornrapee,Brinck, Tore,Ramstroem, Olof. "Phosphine-catalyzed disulfide metathesis". scheme or table. p. 6603 - 6605. Retrieved 2009/04/20.