Phenol, nickel(2+) salt

Base Information

• Chemical Name: Phenol, nickel(2+) salt
• CAS No.: 22535-23-5
• Molecular Formula: C6H6O.1/2Ni
• Molecular Weight: 244.9
• Mol file: 22535-23-5.mol

Synonyms:

Chemical Property of Phenol, nickel(2+) salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenol, nickel(2+) salt

There total 6 articles about Phenol, nickel(2+) salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 28.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + phenyl propionate (637-27-4,132899-52-6) + triethylphosphine (554-70-1) → (CO)2Ni(P(C2H5)3)2 (16787-33-0) + ethane (74-84-0) + ethene (74-85-1) + nickel phenoxide (22535-23-5)

Guidance literature:

In 1,2,5-trimethyl-benzene; (N2 or Ar or vac.), mesitylene added to mixture of Ni(cod)2 and PEt3 and EtCOOPh (PEt3/Ni = 2), mixture stirred at 55°C for 27 h; volumetry, GLC, IR; Kinetics;

DOI:10.1021/ja00531a016

Reference yield: 20.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + Phenyl acetate (122-79-2,34474-31-2) → methane (34557-54-5,27936-85-2) + Ni(CH3)(OC6H5)(C10H8N2) (72918-80-0) + Ni(CO)2(C10H8N2)2 + nickel phenoxide (22535-23-5)

Guidance literature:

With (C₅H₄N)2; In neat (no solvent); byproducts: C2H6; (N2 or Ar or vac.), MeCOOPh added to Ni(cod)2 and bpy ( bpy/Ni = 1.2), mixture stirred at 10°C for 12 h; GLC, IR;

DOI:10.1021/ja00531a016

Reference yield: 17.0%

bis(1,5-cyclooctadiene)nickel (0) (1295-35-8) + Phenyl acetate (122-79-2,34474-31-2) → (triphenylphosphine)3(CO)nickelk (15376-83-7) + methane (34557-54-5,27936-85-2) + ethane (74-84-0) + nickel phenoxide (22535-23-5)

Guidance literature:

With triphenylphosphine; In neat (no solvent); byproducts: anisole; (N2 or Ar or vac.), MeCOOPh added to Ni(cod)2 and PPh3 ( PPh3/Ni = 1.5), mixture stirred at 53°C for 30 h, cooled to room temp.; recrystd. from THF-hexane, hexane added; GLC, IR;

DOI:10.1021/ja00531a016

upstream raw materials:

bis(1,5-cyclooctadiene)nickel ⁽⁰⁾

Phenyl acetate

phenyl propionate

triethylphosphine

Refernces