Deoxybenzoin Oxime

Base Information

• Chemical Name: Deoxybenzoin Oxime
• CAS No.: 26306-06-9
• Molecular Formula: C14H13NO
• Molecular Weight: 211.263
• Hs Code.: 2928000090
• Mol file: 26306-06-9.mol

Synonyms:(E)-1,2-diphenylethanone oxime;1,2-Diphenylethanone oxime;Desoxybenzoin-seqtrans-oxim;benzyl phenyl ketoxime;deoxybenzoin-seqtrans-oxime;DeoxyBenzoinOxime;

Chemical Property of Deoxybenzoin Oxime

Chemical Property:

• Melting Point: 98 °C
• Boiling Point: 375.4±21.0 °C(Predicted)
• PKA: 11.29±0.70(Predicted)
• PSA: 32.59000
• Density: 1.04±0.1 g/cm3(Predicted)
• LogP: 3.10760
• Storage Temp.: -20°C Freezer, Under inert atmosphere
• Solubility.: Chloroform (Slightly), Methanol (Slightly)

Purity/Quality:

98%Min ^*data from raw suppliers

DeoxybenzoinOxime ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Deoxybenzoin Oxime (cas# 26306-06-9) is a compound useful in organic synthesis.

Technology Process of Deoxybenzoin Oxime

There total 10 articles about Deoxybenzoin Oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

phenyl benzyl ketone (451-40-1) → (E)-benzyl phenyl ketoxime (26306-06-9)

Guidance literature:

With pyridine; hydroxylamine hydrochloride; Heating;

Reference yield: 50.0%

styrene (100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6) + benzenediazonium tetrafluoroborate (369-57-3) → (E)-benzyl phenyl ketoxime (26306-06-9)

Guidance literature:

With ferrous(II) sulfate heptahydrate; nitrogen monoxide; In water; dimethyl sulfoxide; aq. acetate buffer; Inert atmosphere;

DOI:10.1002/chem.201101565

Reference yield:

phenyl benzyl ketone (451-40-1) → (E)-benzyl phenyl ketoxime (26306-06-9) + (Z)-1,2-diphenylethanone oxime (57736-10-4)

Guidance literature:

With potassium hydroxide; hydroxylamine hydrochloride; In methanol; water; at 20 ℃;

DOI:10.1021/ja0118791

upstream raw materials:

phenyl benzyl ketone

(E)-(1-nitroethene-1,2-diyl)dibenzene

phenylacetyl chloride

benzene

Downstream raw materials:

2,N-diphenylacetamide

2,N',N'-triphenyl-acetamidine

phenyl benzyl ketone

N-phenyl benzoyl amide

Refernces

• 1、 Xu, Ze-Feng,Zhang, Teng,Hong, Wenjun. "o-Phthalic Anhydride/Zn(OTf)2 co-catalyzed Beckmann rearrangement under mild conditions". supporting information. p. 3113 - 3117. Retrieved 2019/05/08.
• 2、 De Salas, Cristina,Heinrich, Markus R.. "Fixation and recycling of nitrogen monoxide through carbonitrosation reactions". supporting information. p. 2982 - 2987. Retrieved 2014/06/10.