S-Bioallethrin (28434-00-6),S-Bioallethrin (28434-00-6) Manufacturers & Suppliers,Synthesis,MSDS

Basic information

Name:
S-Bioallethrin
CAS No.:
28434-00-6
Molecular Structure:
Formula:
C₁₉H₂₆O₃
Molecular Weight:
302.45
Deleted CAS:
28057-48-9|28991-27-7|22467-86-3
Synonyms:
Cyclopropanecarboxylicacid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-,(1S)-2-methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl ester, (1R,3R)- (9CI);Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-,2-methyl-4-oxo-3-(2-propenyl)-2-cyclopenten-1-yl ester, [1R-[1a(S*),3b]]-;Cyclopropanecarboxylic acid,2,2-dimethyl-3-(2-methylpropenyl)-, trans-(+)-, ester with(+)-2-allyl-4-hydroxy-3-methyl-2-cyclopenten-1-one (8CI);(+)-trans-Allethrin;AI 3-29024;Esbioallethrin;Esbiol;Esdepallethrin;Esdepallethrine;Wasp Killer II;d-Allethrolone chrysanthemumate;d-Allethroloned-trans-chrysanthemate;d-trans-(1-Methyl-2-allyl-3-oxo-1-cyclopenten-5-yl)chrysanthemumate;d-trans-Allethrin;trans-(+)-Allethrin;
EINECS:
249-013-5
Density:
1.05 g/cm³
Boiling Point:
386.8 °C at 760 mmHg
Flash Point:
166 °C
Solubility:
insoluble in water
Appearance:
Clear to amber viscous liquid
Hazard Symbols:
Xn, N
Risk Codes:
20/22-50/53
Safety Description:
36-60-61 Details
Transport Information:
UN3082 9/PG 3

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Chemistry

IUPAC Name: [(1S)-2-Methyl-4-oxo-3-prop-2-enylcyclopent-2-en-1-yl](1R,3R)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate
Canonical SMILES: CC1=C(C(=O)CC1OC(=O)C2C(C2(C)C)C=C(C)C)CC=C
Isomeric SMILES: CC1=C(C(=O)C[C@@H]1OC(=O)[C@@H]2[C@H](C2(C)C)C=C(C)C)CC=C
InChI: InChI=1S/C19H26O3/c1-7-8-13-12(4)16(10-15(13)20)22-18(21)17-14(9-11(2)3)19(17,5)6/h7,9,14,16-17H,1,8,10H2,2-6H3/t14-,16+,17+/m1/s1
InChIKey: ZCVAOQKBXKSDMS-PVAVHDDUSA-N
Molecular Formula: C₁₉H₂₆O₃
Molar mass: 302.41 g/mol
Density: 1.05 g/cm³
Flash Point: 166 °C
storage temp.: 2-8 °C
Water solubility: insoluble
Index of Refraction: 1.515
Molar Refractivity: 86.75 cm³
Molar Volume: 287.5 cm³
Boiling Point: 386.8 °C at 760 mmHg
Vapour Pressure: 3.46E-06 mmHg at 25 °C
Appearance: Clear to amber viscous liquid
EINECS: 249-013-5
Product Categories: INSECTICIDE; Alpha sort; E; E-GAlphabetic; EQ - EZ; Pesticides & Metabolites

Uses

S-Bioallethrin (CAS NO.28434-00-6) can be used for insecticides,fertilizer and pesticides.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
chicken	LD50	oral	> 5gm/kg (5000mg/kg)		Pesticide Manual. Vol. 9, Pg. 78, 1991.
frog	LD50	subcutaneous	1700ug/kg (1.7mg/kg)	BEHAVIORAL: TREMOR BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA	Pesticide Biochemistry and Physiology. Vol. 20, Pg. 217, 1983.
mouse	LC50	inhalation	2720mg/m3/3H (2720mg/m3)	BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA KIDNEY, URETER, AND BLADDER: OTHER CHANGES	EHP, Environmental Health Perspectives. Vol. 14, Pg. 15, 1976.
mouse	LD50	oral	250mg/kg (250mg/kg)	BEHAVIORAL: TREMOR BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA	EHP, Environmental Health Perspectives. Vol. 14, Pg. 15, 1976.
mouse	LD50	subcutaneous	2600mg/kg (2600mg/kg)		Yakkyoku. Pharmacy. Vol. 28, Pg. 1451, 1977.
rabbit	LD50	skin	1545mg/kg (1545mg/kg)		Pesticide Manual. Vol. 9, Pg. 78, 1991.
rat	LC50	inhalation	1600mg/m3/3H (1600mg/m3)	BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA KIDNEY, URETER, AND BLADDER: OTHER CHANGES	EHP, Environmental Health Perspectives. Vol. 14, Pg. 15, 1976.
rat	LD50	oral	430mg/kg (430mg/kg)	SENSE ORGANS AND SPECIAL SENSES: CHROMODACYRORREA: EYE BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA	EHP, Environmental Health Perspectives. Vol. 14, Pg. 15, 1976.
rat	LD50	skin	25gm/kg (25000mg/kg)		Yakkyoku. Pharmacy. Vol. 35, Pg. 1315, 1984.

Safety Profile

Deadly poison by subcutaneous route. Poison by ingestion. Moderately toxic by inhalation. A combustible liquid. When heated to decomposition it emits acrid and irritating fumes. An insecticide.
Hazard Codes: Harmful Xn, Dangerous N
Risk Statements:
R20/22:Harmful by inhalation and if swallowed.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:
S36: Wear suitable protective clothing.
S60: This material and/or its container must be disposed of as hazardous waste.
S61: Avoid release to the environment. Refer to special instructions safety data sheet.
RIDADR: UN3082 9/PG 3
RTECS: GZ1472000

Specification

S-Bioallethrin (CAS NO.28434-00-6), its Synonyms are Bioallethrin ; (+)-Allethronyl (+)-trans-chrysanthemumate ; (S)-3-Allyl-3-methyl-4-oxocyclopent-2-enyl (+)-trans-chrysanthemate ; Esbioallethrin ; Esbiol ; Esbiol concentrate 90% ; Esdepallethrine ; Wasp Killer II ; d-Allethrolone chrysanthemumate ; d-Allethrolone d-trans-chrysanthemumate ; d-T-Allethrin ; d-trans-(1-Methyl-2-allyl-3-oxo-1-cyclopenten-5-yl)chrysanthemumate ; d-trans-Allethrin ; trans-(+)-Allethrin .