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Salcomine

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Name

Salcomine

EINECS 238-012-5
CAS No. 14167-18-1 Density N/A
PSA 43.18000 LogP 1.78200
Solubility Insoluble in water. Soluble in benzene, chloroform, and pyridine. Melting Point >300 °C
Formula C16H14CoN2O2 Boiling Point 498.2ºC at 760 mmHg
Molecular Weight 325.293 Flash Point N/A
Transport Information N/A Appearance black crystalline powder
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 14167-18-1 (Salcomine) Hazard Symbols IrritantXi
Synonyms

Cobalt salen;N,N'-Ethylenebis(salicylideniminato)cobalt(II);NSC 32965;Salcomin;Salcomine;[2,2'-[Ethane-1,2-diylbis(nitrilomethylidene)]diphenolato]cobalt(II);[Bis(salicylidene)ethylenediaminato]cobalt;[Bis(salicylidene)ethylenediamine]cobalt;[N,N'-Bis(salicylidene)ethylenediaminato]cobalt;[N,N'-Disalicylideneethylenediamine]cobalt;[N,N'-Ethylenebis(salicylaldehydeiminato)]cobalt(II);[N,N'-Ethylenebis(salicylideniminato)]cobalt;Cobalt,[[2,2'-[1,2-ethanediylbis(nitrilomethylidyne)]bis[phenolato]](2-)-N,N',O,O']-,(SP-4-2)-;Cobalt, [[a,a'-(ethylenedinitrilo)di-o-cresolato](2-)]-(7CI,8CI);o-Cresol, a,a'-(ethylenedinitrilo)di-, Coderiv. (6CI);(N,N'-Bis(salicylidene)ethylenediamine)cobalt(II);Bis(salicylidene)ethylenediaminatocobalt(II);Co(salen);Cobaltbis(salicylidene)ethylenediamine;

Article Data 46

Salcomine Consensus Reports

Reported in EPA TSCA Inventory. Cobalt and its compounds are on the Community Right-To-Know List. EPA Extremely Hazardous Substances List.

Salcomine Specification

The Salcomine, with the CAS registry number 14167-18-1 and EINECS registry number 238-012-5, has the IUPAC name of cobalt(2+); 2-[2-[(2-oxidophenyl)methylideneamino]ethyliminomethyl]phenolate. And the molecular formula of this chemical is C16H14CoN2O2. It is a kind of black crystalline powder, and belongs to the following product categories: Catalysts for Organic Synthesis; Classes of Metal Compounds; Co (Cobalt) Compounds; Homogeneous Catalysts; Metal Complexes; Synthetic Organic Chemistry; Transition Metal Compounds.

The physical properties of Salcomine are as following: (1)#H bond acceptors: 4; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 43.18 Å2.

Preparation and uses of Salcomine: It can be easily synthesized from cobalt(II) acetate and salenH2. And it reversibly bound O2 led to intensive research on salen and related ligands for the storage or transport of oxygen. It is used as catalyst in the oxidation of 2,6-disubstituted phenols by dioxygen.

You should be cautious while dealing with this chemical. It irritates eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: C1CN=Cc3ccccc3O[Co]Oc2ccccc2C=N1
(2)InChI: InChI=1/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2
(3)InChIKey: NPAQSKHBTMUERN-NUQVWONBAY

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LCLo inhalation 390mg/m3/5.5H (390mg/m3) LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHI

LUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA

LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES
Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974,

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