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Selenious acid, dipotassium salt

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Name

Selenious acid, dipotassium salt

EINECS N/A
CAS No. 10431-47-7 Density g/cm3
PSA 63.19000 LogP -0.73720
Solubility Soluble in ethyl alcohol, water. Melting Point 875°C (dec.)
Formula H2O3 Se . 2 K Boiling Point °Cat760mmHg
Molecular Weight 205.155 Flash Point °C
Transport Information N/A Appearance N/A
Safety A poison and corrosive. When heated to decomposition it emits toxic vapors of selinium. Risk Codes 23/25-33-50/53-36/37/38-23/24/25
Molecular Structure Molecular Structure of 10431-47-7 (POTASSIUM SELENITE) Hazard Symbols
Synonyms

Potassiumselenite (K2SeO3) (6CI,7CI); Selenious acid (H2SeO3), dipotassium salt;Selenious acid, dipotassium salt (9CI); Dipotassium selenite; Potassiumselenite

 

Selenious acid, dipotassium salt Synthetic route

7446-08-4

selenium(IV) oxide

584-08-7

potassium carbonate

10431-47-7

KO3Se(1-)*K(1+)

Conditions
ConditionsYield
In neat (no solvent, solid phase) metal carbonate is reacted with solid SeO2 (fusion);

Selenious acid, dipotassium salt Chemical Properties

Molecule structure of Selenious acid, dipotassium salt (CAS NO.10431-47-7) :

IUPAC Name: dipotassium selenite 
Molecular Weight: 205.1548 g/mol
Molecular Formula: K2O3Se 
Density: 2.851^1^5
Melting Point: 875°C (dec.)
Sensitive: hygroscopic
H-Bond Acceptor: 3
Exact Mass: 205.828679
MonoIsotopic Mass: 205.828679
Topological Polar Surface Area: 63.2
Heavy Atom Count: 6
Complexity: 18.8
Canonical SMILES: [O-][Se](=O)[O-].[K+].[K+]
InChI: InChI=1S/2K.H2O3Se/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2
InChIKey: RNGFNLJMTFPHBS-UHFFFAOYSA-L
EINECS: 233-909-8

Selenious acid, dipotassium salt Consensus Reports

Reported in EPA TSCA Inventory.

Selenious acid, dipotassium salt Safety Profile

A poison and corrosive. When heated to decomposition it emits toxic vapors of selinium.
Hazard Codes: ToxicT
Risk Statements: 23/25-33-50/53-36/37/38-23/24/25 
R23/25:Toxic by inhalation and if swallowed. 
R33:Danger of cumulative effects. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 20/21-28-45-36/37/39-26-22 
S20:When using, do not eat or drink. 
S21:When using do not smoke. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S22:Do not breathe dust.
RIDADR: 2630
RTECS: VS7200000
HazardClass: 6.1
PackingGroup: I

Selenious acid, dipotassium salt Standards and Recommendations

DOT Classification:  6.1; Label: Poison, Corrosive

Selenious acid, dipotassium salt Specification

 Selenious acid, dipotassium salt (CAS NO.10431-47-7) is also called CCRIS 6885 ; Dipotassium selenite ; Potassium selenite ; Selenious acid, potassium salt (1:2) . Salts, basic, such as Selenious acid, dipotassium salt (CAS NO.10431-47-7) , are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Selenious acid, dipotassium salt (CAS NO.10431-47-7) is highly toxic. It may be fatal if inhaled, swallowed or absorbed through skin. People must avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Containers may explode when heated. Runoff may pollute waterways.

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