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Silicon tetrafluoride

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Name

Silicon tetrafluoride

EINECS 232-015-5
CAS No. 7783-61-1 Density 1.209 g/cm3
PSA 0.00000 LogP 1.30000
Solubility N/A Melting Point -90°C
Formula F4Si Boiling Point 86 °C
Molecular Weight 104.079 Flash Point N/A
Transport Information UN 1859 Appearance COLOURLESS GAS , WITH PUNGENT ODOUR.
Safety 7/9-24/25-45-36/37/39-26-23 Risk Codes 26-35-34-31-26/27/28-14
Molecular Structure Molecular Structure of 7783-61-1 (Tetrafluorosilane) Hazard Symbols CorrosiveC; ToxicT; VeryT+
Synonyms

Siliconfluoride (SiF4) (8CI);Perfluorosilane;Silicontetrafluoride;Tetrafluorosilane;

Article Data 522

Silicon tetrafluoride Synthetic route

116-14-3

polytetrafluoroethylene

4168-07-4

(1,1,2,2-tetrafluoroethyl)trifluorosilane

A

433-66-9

pentafloropropylene

B

931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

C

379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

D

7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
at 150℃; for 18h; Further byproducts given;A 5%
B n/a
C 74%
D 100%
at 200℃; for 10h; Further byproducts given;A 19%
B n/a
C 71%
D 98%
4168-07-4

(1,1,2,2-tetrafluoroethyl)trifluorosilane

A

433-66-9

pentafloropropylene

B

379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

C

7783-61-1

silicon tetrafluoride

D

359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
With polytetrafluoroethylene at 150℃; for 18h; Further byproducts given;A 5%
B 74%
C 100%
D 10%
353-50-4

Carbonyl fluoride

A

124-38-9

carbon dioxide

B

7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
In neat (no solvent) slight excess over the stoich. amt. of COF2 required; reaction mixt. heated in a stainless steel or monel cylinder at 160°C for 36 h;A n/a
B 100%

sodium hexafluorosilicate

7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
In neat (no solvent) salt dried at 250°C in vac. or in N2 flow; thermal dissocn. at 500-620°C in vac. in stainless steel reactor; fed into metallic cylinder cooled with liq. N2; filtration, IR, atomic emission and mass spectrometry;100%
With water In neat (no solvent) byproducts: Si2OF6, SiF3OH, SiF3H; predrying of Na2SiF6 at 250-300.C in vac. or N2 for several hours, heating at 500 to 620°C in stainless steel reactor; cooling with liquid N2;
With sulfuric acid In sulfuric acid reaction by use of concd. H2SO4;;
54939-02-5

(2,2-dichloro trifluoro ethyl) trifluoro silane

A

79-35-6

1,1'-dichloro-2,2'-difluoroethene

B

598-88-9

1,2-dichloro-1,2-difluoroethene

C

7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
In neat (no solvent) pyrolysis at 140°C, 3 hours;;A 8%
B 90%
C 100%
In neat (no solvent) pyrolysis at 140°C, 3 hours;;A 8%
B 90%
C 100%
6651-55-4

diphenylfluorostibine

368-47-8

phenyltrifluorosilane

A

603-36-1

triphenylantimony

B

7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
reflux for 3 d;A 100%
B n/a
reflux for 3 d;A 100%
B n/a
563-79-1

2,3-Dimethyl-2-butene

4168-07-4

(1,1,2,2-tetrafluoroethyl)trifluorosilane

A

17216-38-5

1-fluoro-1-difluoromethyl-2,2,3,3-tetramethylcyclopropane

B

7783-61-1

silicon tetrafluoride

C

359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
at 150℃; for 16h;A 86%
B 99%
C 6%
379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

110-83-8

cyclohexene

A

116-14-3

polytetrafluoroethylene

B

433-66-9

pentafloropropylene

C

201230-82-2

carbon monoxide

D

115-25-3

Octafluorocyclobutane

E

823-70-1

7,7-difluoronorcarane

F

7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
With Pyrex tube at 200℃; for 320h; Product distribution; Mechanism; further periods of contact time, other temperatures;A 14%
B 99%
C 11%
D n/a
E 47%
F 13%
116-14-3

polytetrafluoroethylene

4168-07-4

(1,1,2,2-tetrafluoroethyl)trifluorosilane

A

433-66-9

pentafloropropylene

B

379-14-6

1,2,2,3,3-pentafluoro-1-difluoromethylcyclopropane

C

7783-61-1

silicon tetrafluoride

D

359-11-5

1,1,2-trifluoroethylene

Conditions
ConditionsYield
at 200℃; for 10h; Further byproducts given;A 19%
B 71%
C 98%
D 8%
75-44-5

phosgene

sodium fluoride

A

353-50-4

Carbonyl fluoride

B

353-49-1

fluoroformyl chloride

C

124-38-9

carbon dioxide

D

7783-61-1

silicon tetrafluoride

Conditions
ConditionsYield
In acetonitrile condensation, 20°C in a sealed Pyrex tube, staying 24 h at 20°C;A 97%
B 0%
C n/a
D <1

Silicon tetrafluoride Consensus Reports

Reported in EPA TSCA Inventory.

Silicon tetrafluoride Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F)/m3
DOT Classification:  2.3; Label: Poison Gas, Corrosive

Silicon tetrafluoride Specification

The CAS registry number of Silicon tetrafluoride is 7783-61-1. The IUPAC name is tetrafluorosilane. Its EINECS registry number is 232-015-5. In addition, the molecular formula is F4Si and the molecular weight is 104.08. This tetrahedral molecule is notable for having a remarkably narrow liquid range (its boiling point is only 4 °C above its melting point).

Physical properties about this chemical are: (1)ACD/LogP: 4.15; (2)ACD/LogD (pH 5.5): 4.15; (3)ACD/LogD (pH 7.4): 4.15; (4)ACD/BCF (pH 5.5): 837.56; (5)ACD/BCF (pH 7.4): 837.56; (6)#Freely Rotating Bonds: 0; (7)Polar Surface Area: 0 Å2; (8)Index of Refraction: 1.207; (9)Molar Refractivity: 11.42 cm3; (10)Molar Volume: 86 cm3; (11)Polarizability: 4.52 ×10-24cm3; (12)Surface Tension: 5.1 dyne/cm; (13)Density: 1.209 g/cm3; (14)Enthalpy of Vaporization: 17.05 kJ/mol; (15)Vapour Pressure: 26400 mmHg at 25°C.

Preparation of Silicon tetrafluoride: it is a by-product of the production of phosphate fertilizers, resulting from the attack of HF(derived from fluorapatite protonolysis) on silicates. It is prepared by heating BaSiF6(>300 °C). In addition, the required BaSiF6 is prepared by treating aqueous hexafluorosilicic acid with barium chloride.

Uses of Silicon tetrafluoride: it can be used to get fluorine silicate and fluoride lead. And it can be used as a stiffening agent of cement and artificial marble, also used for synthetic materials of organic silicon compounds.

When you are using this chemical, please be cautious about it as the following:
This chemical can react violently with water and can cause severe burns. If it contact with acids, it will liberate toxic gas. And it is very Toxic by inhalation, in contact with skin and if swallowed. During using it, wear suitable protective clothing, gloves and eye/face protection and avoid contact with skin and eyes. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). After using it, keep container tightly closed and in a well-ventilated place.

You can still convert the following datas into molecular structure:
(1)SMILES: F[Si](F)(F)F
(2)InChI: InChI=1/F4Si/c1-5(2,3)4
(3)InChIKey: ABTOQLMXBSRXSM-UHFFFAOYAU

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LC50 inhalation 2272ppm (2272ppm) SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE

LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Journal of Toxicological Sciences. Vol. 18, Pg. 394, 1993.

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